Rh(I)-Catalyzed [5+1] Cycloaddition of Vinylcyclopropanes and CO for the Synthesis of α,β- and β,γ-Cyclohexenones

被引：67

作者：

Jiang, Guo-Jie ^{[1
]}

Fu, Xu-Fei ^{[1
]}

Li, Qui ^{[1
]}

Yu, Zhi-Xiang ^{[1
]}

机构：

[1] Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, BNLMS, Beijing 100871, Peoples R China

来源：

ORGANIC LETTERS | 2012年 / 14卷 / 03期

关键词：

CARBON-MONOXIDE; ORGANIC-SYNTHESIS; ALKENYL CYCLOPROPANES; IRON CARBONYL; METAL; RING; CYCLOHEXENONES; OCTACARBONYLDICOBALT; TRANSFORMATION; 1-(1,2-PROPADIENYL)CYCLOPROPANOLS;

D O I：

10.1021/ol2031526

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A cationic Rh(I)-catalyzed [5 + 1] cycloaddition of vinylcyclopropanes and CO has been developed, affording either beta,gamma-cyclohexenones as major products or alpha,beta-cyclohexenones exclusively, under different reaction conditions.

引用

页码：692 / 695

页数：4

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