Production, Mechanical Properties and Biomedical Characterization of ZrTi-Based Bulk Metallic Glasses in Comparison with 316L Stainless Steel and Ti6Al4V Alloy

被引：18

作者：

Hasiak, Mariusz ^{[1
]}

Sobieszczanska, Beata ^{[2
]}

Laszcz, Amadeusz ^{[1
]}

Bialy, Michal ^{[1
]}

Checmanowski, Jacek ^{[3
]}

Zatonski, Tomasz ^{[4
]}

Bozemska, Edyta ^{[2
]}

Wawrzynska, Magdalena ^{[5
]}

机构：

[1] Wroclaw Univ Sci & Technol, Dept Mech Mat & Biomed Engn, Smoluchowskiego 25, PL-50370 Wroclaw, Poland

[2] Wroclaw Med Univ, Dept Microbiol, T Chalubinskiego 4, PL-50368 Wroclaw, Poland

[3] Wroclaw Univ Sci & Technol, Dept Adv Mat Technol, 25 Smoluchowskiego, PL-50370 Wroclaw, Poland

[4] Wroclaw Med Univ, Dept & Clin Otolaryngol Head & Neck Surg, Borowska 213, PL-50556 Wroclaw, Poland

[5] Wroclaw Med Univ, Ctr Preclin Studies, Ludwika Pasteura 1, PL-50367 Wroclaw, Poland

来源：

MATERIALS | 2022年 / 15卷 / 01期

关键词：

biocompatibility; bulk metallic glasses; Zr-based alloys; nanoindentation; fibroblasts; biocorrosion; cytotoxicity; SUPERCOOLED LIQUID; ELECTROCHEMICAL-BEHAVIOR; CORROSION BEHAVIOR; FORMING ABILITY; ELASTIC-MODULUS; CASTING DEVICE; TI-ALLOYS; CO-AL; BIOCOMPATIBILITY; INDENTATION;

D O I：

10.3390/ma15010252

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Microstructure, mechanical properties, corrosion resistance, and biocompatibility were studied for rapidly cooled 3 mm rods of Zr40Ti15Cu10Ni10Be25, Zr50Ti5Cu10Ni10Be25, and Zr40Ti15Cu10Ni5Si5Be25 (at.%) alloys, as well as for the reference 316L stainless steel and Ti-based Ti6Al4V alloy. Microstructure investigations confirm that Zr-based bulk metallic samples exhibit a glassy structure with minor fractions of crystalline phases. The nanoindentation tests carried out for all investigated composite materials allowed us to determine the mechanical parameters of individual phases observed in the samples. The instrumental hardness and elastic to total deformation energy ratio for every single phase observed in the manufactured Zr-based materials are higher than for the reference materials (316L stainless steel and Ti6Al4V alloy). A scratch tester used to determine the wear behavior of manufactured samples and reference materials revealed the effect of microstructure on mechanical parameters such as residual depth, friction force, and coefficient of friction. Electrochemical investigations in simulated body fluid performed up to 120 h show better or comparable corrosion resistance of Zr-based bulk metallic glasses in comparison with 316L stainless steel and Ti6Al4V alloy. The fibroblasts viability studies confirm the good biocompatibility of the produced materials. All obtained results show that fabricated biocompatible Zr-based materials are promising candidates for biomedical implants that require enhanced mechanical properties.

引用

页数：19

共 100 条

[11] THERMODYNAMIC CONSIDERATIONS ON FORMATION AND STABILITY OF METALLIC GLASSES [J].

CHEN, HS .

ACTA METALLURGICA, 1974, 22 (12) :1505-1511

[12] Tribological characterisation of Zr-based bulk metallic glass in simulated physiological media [J].

Chen, Q. ;

Chan, K. C. ;

Liu, L. .

PHILOSOPHICAL MAGAZINE, 2011, 91 (28) :3705-3715

[13] Metallic implant biomaterials [J].

Chen, Qizhi ;

Thouas, George A. .

MATERIALS SCIENCE & ENGINEERING R-REPORTS, 2015, 87 :1-57

[14] Hardness variation across a Zr57Ti5Cu20Ni8Al10 bulk metallic glass [J].

Chen, Rong ;

Yang, Fuqian ;

Fan, Guojiang ;

Liaw, Peter K. .

JOURNAL OF MATERIALS SCIENCE, 2007, 42 (06) :2208-2211

[15] Correlation of the microstructure and mechanical properties of Zr-based in-situ bulk metallic glass matrix composites [J].

Cheng, J. L. ;

Chen, G. ;

Xu, F. ;

Du, Y. L. ;

Li, Y. S. ;

Liu, C. T. .

INTERMETALLICS, 2010, 18 (12) :2425-2430

[16] SIMPLE CASTING DEVICE FOR USE WITH AN ARGON ARC FURNACE [J].

CROW, JE ;

SWEEDLER, AR .

REVIEW OF SCIENTIFIC INSTRUMENTS, 1973, 44 (09) :1398-1398

[17] Monolithic Ceramics: Effect of Finishing Techniques on Surface Properties, Bacterial Adhesion and Cell Viability [J].

Dal Piva, A. M. O. ;

Contreras, L. P. C. ;

Ribeiro, F. C. ;

Anami, L. C. ;

Camargo, S. E. A. ;

Jorge, A. O. C. ;

Bottino, M. A. .

OPERATIVE DENTISTRY, 2018, 43 (03) :315-325

[18] AMORPHOUS PHASE IN PALLADIUM-SILICON ALLOYS [J].

DUWEZ, P ;

WILLENS, RH ;

CREWDSON, RC .

JOURNAL OF APPLIED PHYSICS, 1965, 36 (07) :2267-&

[19] Recent developments in ductile bulk metallic glass composites [J].

Ferry, M. ;

Laws, K. J. ;

White, C. ;

Miskovic, D. M. ;

Shamlaye, K. F. ;

Xu, W. ;

Biletska, O. .

MRS COMMUNICATIONS, 2013, 3 (01) :1-12

[20] Enhanced mechanical properties and in vitro corrosion behavior of amorphous and devitrified Ti40Zr10Cu38Pd12 metallic glass [J].

Fornell, J. ;

Van Steenberge, N. ;

Varea, A. ;

Rossinyol, E. ;

Pellicer, E. ;

Surinach, S. ;

Baro, M. D. ;

Sort, J. .

JOURNAL OF THE MECHANICAL BEHAVIOR OF BIOMEDICAL MATERIALS, 2011, 4 (08) :1709-1717

← 1 2 3 4 5 6 7 8 9 10 →