Sulfoxide-Mediated α-Arylation of Carbonyl Compounds

被引：139
作者：
Huang, Xueliang [1 ]
Maulide, Nuno [1 ]
机构：
[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 22期
关键词：
PUMMERER REACTION CHEMISTRY; ARYLKETENE DITHIOACETAL MONOXIDES; BETA-DICARBONYL COMPOUNDS; QUATERNARY STEREOCENTERS; OXIDATIVE CYCLIZATION; ASYMMETRIC-SYNTHESIS; ORGANOBISMUTH REAGENTS; DIARYLIODONIUM SALTS; BOND FORMATION; ALDEHYDES;
D O I：
10.1021/ja2031882
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel sulfoxide-mediated alpha-arylation of carbonyl compounds is reported. This reaction proceeds under very mild conditions at room temperature and does not require any transition-metal promoter or catalyst.
引用
收藏
页码：8510 / 8513
页数：4
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