Kinetics and mechanism of oxidation of substituted benzyl alcohol by polymer supported oxidizing agent

被引：0

作者：

Jawanjal, AL ^{[1
]}

Hilage, NP ^{[1
]}

机构：

[1] Shivaji Univ, Dept Chem, Kolhapur 416004, Maharashtra, India

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2005年 / 44卷 / 09期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetics of oxidation of monosubstituted benzyl alcohol with polymer supported chromic acid in 1:4 dioxane has been studied. The reaction is found to be of zero order each in [alcohol] and [oxidant]. The effect of substituent on the rate of oxidation and the thermodynamic parameters are evaluated. The reaction products have been isolated and characterised by their derivatives. A probable mechanism of oxidation is proposed,

引用

页码：1827 / 1830

页数：4

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