The Kabachnik-Fields Reaction in the Synthesis of Polyaminophosphonate Derivatives of p-tert-Butylthiacalix[4]arene

被引：0

作者：

Shibaeva, K. S. ^{[1
]}

Mostovaya, O. A. ^{[1
]}

Nazarova, A. A. ^{[1
]}

Shurpik, D. N. ^{[1
]}

Shiabiev, I. E. ^{[1
]}

Kuznetsova, D. I. ^{[1
]}

Stoykov, I. I. ^{[1
]}

机构：

[1] Kazan Fed Univ, Butlerov Chem Inst, Ul Kremlevskaya 18, Kazan 420008, Tatarstan, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2018年 / 88卷 / 09期

基金：

俄罗斯基础研究基金会;

关键词：

Kabachnik-Fields reaction; thiacalix[4]arene; aminophosphonate; AMINO-ACIDS; AMINOPHOSPHONIC ACIDS; MOLECULAR RECOGNITION; FUNCTIONALIZATION; COMPLEXATION; AMIDE;

D O I：

10.1134/S1070363218090086

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel derivatives of p-tert-butylthiacalix[4]arene containing four or eight 1-aminophosphonate groups at the lower rim of the macrocycle in 1,3-alternate conformation have been synthesized via the Kabachnik-Fields reaction. These compounds are promising synthetic receptors for biologically important acids. It has been shown that complete phosphorylation of the first generation dendrimer containing eight primary amino groups is impeded in the case of cyclic ketones.

引用

页码：1812 / 1817

页数：6