Piezoelectric Energy Harvesting from a Ferroelectric Hybrid Salt [Ph3MeP]4[Ni(NCS)6] Embedded in a Polymer Matrix

被引:44
作者
Vijayakanth, Thangavel [1 ]
Ram, Farsa [2 ,3 ]
Praveenkumar, Balu [4 ]
Shanmuganathan, Kadhiravan [2 ,3 ]
Boomishankar, Ramamoorthy [1 ]
机构
[1] Indian Inst Sci Educ & Res, Dept Chem & Ctr Energy Sci, Dr Homi Bhabha Rd, Pune 411008, Maharashtra, India
[2] CSIR Natl Chem Lab, Polymer Sci & Engn Div, Dr Homi Bhabha Rd, Pune 411008, Maharashtra, India
[3] CSIR Natl Chem Lab, Acad Sci & Innovat Res, Dr Homi Bhabha Rd, Pune 411008, Maharashtra, India
[4] Armament Res & Dev Estab, PZT Ctr, Dr Homi Bhabha Rd, Pune 411021, Maharashtra, India
关键词
energy conversion; mechanical properties; non-covalent interactions; organic-inorganic hybrid composites; phosphorus; ENHANCED PIEZOELECTRICITY; OUTPUT PERFORMANCE; FILMS; NANOGENERATOR; COMPOSITES; GENERATORS; PHASE;
D O I
10.1002/anie.202001250
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Organic-inorganic hybrid ferroelectrics are an exciting class of molecular materials with promising applications in the area of energy and electronics. The synthesis, ferroelectric and piezoelectric energy harvesting behavior of a 3d metal ion-containing A(4)BX(6) type organic-inorganic hybrid salt [Ph3MeP](4)[Ni(NCS)(6)] (1) is now presented. P-E hysteresis loop studies on 1 show a remnant ferroelectric polarization value of 18.71 mu C cm(-2), at room temperature. Composite thermoplastic polyurethane (TPU) devices with 5, 10, 15 and 20 wt % compositions of 1 were prepared and employed for piezoelectric energy harvesting studies. A maximum output voltage of 19.29 V and a calculated power density value of 2.51 mW cm(-3) were observed for the 15 wt % 1-TPU device. The capacitor charging experiments on the 15 wt % 1-TPU composite device shows an excellent energy storage performance with the highest stored energies and measured charges of 198.8 mu J and 600 mu C, respectively.
引用
收藏
页码:10368 / 10373
页数:6
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