X-ray diffraction, Raman spectrum and magnetic susceptibility of the magnetic semiconductor Cu2FeSnS4

被引:55
|
作者
Rincon, C. [1 ]
Quintero, M. [1 ]
Moreno, E. [1 ]
Power, Ch. [1 ]
Quintero, E. [1 ]
Henao, J. A. [2 ]
Macias, M. A. [2 ]
Delgado, G. E. [3 ]
Tovar, R. [1 ]
Morocoima, M. [1 ]
机构
[1] Univ Los Andes, Fac Ciencias, Dept Fis, Ctr Estudios Semicond, Merida 5101, Venezuela
[2] Univ Ind Santander, Escuela Quim, Fac Ciencias, Grp Invest Quim Estruct, Bucaramanga, Colombia
[3] Univ Los Andes, Fac Ciencias, Dept Quim, Lab Cristalog, Merida 5101, Venezuela
关键词
Semiconductors; Crystal structure and symmetry; X-ray scattering; Raman scattering; CRYSTAL-STRUCTURE; LATTICE-VIBRATIONS; STANNITE; KESTERITE;
D O I
10.1016/j.ssc.2011.04.002
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
In an attempt to resolve the crystal structure and the corresponding space group of the magnetic semiconductor Cu2FeSnS4, samples of this compound were studied by X-ray diffraction, differential thermal analysis, Raman scattering and magnetic susceptibility. It was found that at room temperature this compound prepared by a careful crystal growth process, including annealing to equilibrium at a suitable temperature followed by slow cooling of the samples to 300 K, crystallizes in a tetragonal structure with space group P (4) over bar. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:947 / 951
页数:5
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