Palladium nanoparticles supported on SiO2 by chemical vapor deposition (CVD) technique as efficient catalyst for Suzuki-Miyaura coupling of aryl bromides and iodides: selective coupling of halophenols

被引：25
作者：
Iranpoor, Nasser [1 ]
Firouzabadi, Habib [1 ]
Safavi, Afsaneh [1 ,2 ]
Motevalli, Somayeh [1 ]
Doroodmand, Mohammad M. [1 ,2 ]
机构：
[1] Shiraz Univ, Dept Chem, Coll Sci, Shiraz, Iran
[2] Shiraz Univ, Nano Technol Res Inst, Shiraz, Iran
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2012年 / 26卷 / 08期
关键词：
silica support; palladium nanoparticle; biphenyls; Suzuki-Miyaura reaction; N-HETEROCYCLIC CARBENE; HIGHLY-ACTIVE CATALYST; COMPLEXES BEARING; ARYLBORONIC ACIDS; CARBON-CARBON; IONIC LIQUID; HECK; PALLADACYCLE; LIGANDLESS; CHLORIDES;
D O I：
10.1002/aoc.2868
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Nanoparticles of palladium were supported on SiO2 by chemical vapor deposition technique. The obtained Pd nanocatalyst was characterized by various techniques. This catalyst was found to be very efficient for the selective cross-coupling of hydroxyl-substituted aryl iodides and bromide with arylboronic acids in water at room temperature to produce the corresponding hydroxyl-substituted biaryls. Coupling of phenylboronic acid with aryl iodides and bromides carrying substituents other than hydroxy group was also performed efficiently in refluxing ethanol. Copyright (c) 2012 John Wiley & Sons, Ltd.
引用
收藏
页码：417 / 424
页数：8
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