Long-range ordering in β-Cu-Zn-Al:: Experimental and theoretical study

被引:19
作者
Lanzini, F. [1 ,2 ]
Romero, R. [1 ,3 ]
Stipcich, M. [1 ,2 ]
Castro, M. L. [1 ,2 ]
机构
[1] Univ Nacl Ctr Provincia Buenos Aires, Fac Ciencias Exactas, IFIMAT, Buenos Aires, DF, Argentina
[2] Consejo Nacl Invest Cient & Tecn, RA-1033 Buenos Aires, DF, Argentina
[3] CICPBA, La Plata, Argentina
来源
PHYSICAL REVIEW B | 2008年 / 77卷 / 13期
关键词
D O I
10.1103/PhysRevB.77.134207
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We present the order-disorder transition temperatures for bcc Cu-Zn-Al shape-memory alloys measured by means of calorimetric and resistometric techniques. The investigation includes the line of compositions Cu(0.76-x/2)-Zn(x)-Al(0.24-x/2) (0 <= x <= 0.48), i.e., the line with a constant conduction electron per atom ratio, e/a=1.48. Experimental results are confronted with Monte Carlo simulations based on the Blume-Emery-Griffiths Hamiltonian. A set of exchange energies in first and second neighbors is calculated, which allows in close agreement reproduction of the experimental phase diagram.
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页数:8
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