Polymerization in a magnetic field. XV Some azoinitiators behavior in a high magnetic field

被引：8

作者：

Chiriac, AP ^{[1
]}

机构：

[1] Petru Poni Inst Macromol Chem, RO-700487 Iasi, Romania

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2005年 / 98卷 / 03期

关键词：

polymerization kinetic; radical polymerization; magnetic field; styrene; thermogravimetric analysis;

D O I：

10.1002/app.22218

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The effect of a high magnetic field of 7 T on styrene polymerization reactions was taken under study. The intervened magnetokinetic modifications are correlated to the system of radical initiation, respectively: benzoyl peroxide, 2, 2'-azobis(2-methylpropionitrile), 4,4'-azobis(4-cyanopentanoic acid), and 1,1'-azobis (cyclohexan-1carbonitrile). The reaction products are also characterized from the viewpoint of their molecular weights correlated with the reaction conditions, as well as their thermal stability. (c) 2005 Wiley Periodicals, Inc.

引用

页码：1025 / 1031

页数：7

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