Mossbauer studies of nanosize Mn1-xZnxFe2O4

被引:71
作者
Upadhyay, C
Verma, HC [1 ]
Rath, C
Sahu, KK
Anand, S
Das, RP
Mishra, NC
机构
[1] Indian Inst Technol, Dept Phys, Kanpur 208016, Uttar Pradesh, India
[2] Natl Met Lab, Jamshedpur 7, Bihar, India
[3] Reg Res Lab, Bhubaneswar 751013, Orissa, India
[4] Ctr Nucl Sci, New Delhi, India
关键词
Mossbauer spectroscopy; ferrites; nanoparticles; spinel; superparamagnetism;
D O I
10.1016/S0925-8388(01)01219-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Nanosized mixed ferrite Mn1-xZnFe2O4 (x = 0.0, 0.35, 0.5, 0.65, 1) has been prepared by hydrothermal route at pH 9 and 210 degreesC and studied by X-ray diffraction, magnetization measurement and Mossbauer spectroscopy. The size of the particles decreases gradually as the zinc concentration is increased. The cation distribution has been found to strongly depend on the process parameters. On annealing the system the cation distribution changes from a metastable state to a stable state which enhances the superparamagnetism. ZnFe2O4 with average particle size of 4 nm. shows magnetic ordering even at room temperature. (C) 2001 Elsevier Science BY All rights reserved.
引用
收藏
页码:94 / 97
页数:4
相关论文
共 7 条
[1]   Magnetic properties of ZnFe2O4 synthesized by ball milling [J].
Goya, GF ;
Rechenberg, HR .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1999, 203 :141-142
[2]  
Hadjipanaysis G.C., 1997, MAGNETIC HYSTERESIS
[3]   Magnetic properties of partially-inverted zinc ferrite aerogel powders [J].
Hamdeh, HH ;
Ho, JC ;
Oliver, SA ;
Willey, RJ ;
Oliveri, G ;
Busca, G .
JOURNAL OF APPLIED PHYSICS, 1997, 81 (04) :1851-1857
[4]   Appearance of superparamagnetism on heating nanosize Mn0.65Zn0.35Fe2O4 [J].
Rath, C ;
Mishra, NC ;
Anand, S ;
Das, RP ;
Sahu, KK ;
Upadhyay, C ;
Verma, HC .
APPLIED PHYSICS LETTERS, 2000, 76 (04) :475-477
[5]   PRODUCTION OF MANGANESE ZINC FERRITES VIA THE HYDROTHERMAL DECOMPOSITION OF METAL(III) ACETATES AND CITRATES [J].
SISK, M ;
KILBRIDE, I ;
BARKER, AJ .
JOURNAL OF MATERIALS SCIENCE LETTERS, 1995, 14 (03) :153-154
[6]   Structure and high magnetization of rapidly quenched zinc ferrite [J].
Tanaka, K ;
Makita, M ;
Shimizugawa, Y ;
Hirao, K ;
Soga, N .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1998, 59 (09) :1611-1618
[7]   HYPERFINE FIELD DISTRIBUTIONS FROM MOSSBAUER SPECTRA [J].
WINDOW, B .
JOURNAL OF PHYSICS E-SCIENTIFIC INSTRUMENTS, 1971, 4 (05) :401-&