Metal-Organic Framework Membranes and Membrane Reactors: Versatile Separations and Intensified Processes

被引:15
作者
Ban, Yujie [1 ]
Cao, Na [1 ,2 ]
Yang, Weishen [1 ]
机构
[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China
[2] Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100039, Peoples R China
基金
中国国家自然科学基金;
关键词
MIXED-MATRIX MEMBRANES; PERVAPORATION DEHYDRATION; ACETIC-ACID; NANOCOMPOSITE MEMBRANE; ETHANOL DEHYDRATION; EFFICIENT RECOVERY; H-2/CO2; SEPARATION; HYBRID MEMBRANES; ZIF-8; PERFORMANCE;
D O I
10.34133/2020/1583451
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Metal-organic frameworks are an emerging and fascinating category of porous solids that can be self-assembled with metal-based cations linked by organic molecules. The unique features of MOFs in porosity (or surface areas), together with their diversity for chemical components and architectures, make MOFs attractive candidates in many applications. MOF membranes represent a long-term endeavor to convert MOF crystals in the lab to potentially industry-available commodities, which, as a promising alternative to distillation, provide a bright future for energy-efficient separation technologies closely related with chemicals, the environment, and energy. The membrane reactor shows a typical intensified process strategy by combining the catalytic reaction with the membrane separation in one unit. This review highlights the recent process of MOF-based membranes and the importance of MOF-based membrane reactors in relative intensified chemical processes.
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页数:13
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