Dual Porous 3D Zinc Anodes toward Dendrite-Free and Long Cycle Life Zinc-Ion Batteries

被引：47
作者：
Chen, Kai [1 ]
Guo, Huinan [1 ]
Li, Weiqin [1 ]
Wang, Yijing [1 ]
机构：
[1] Nankai Univ, Coll Chem, Renewable Energy Convers & Storage Ctr, Key Lab Adv Energy Mat Chem,Minist Educ, Tianjin 300071, Peoples R China
来源：
ACS APPLIED MATERIALS & INTERFACES | 2021年 / 13卷 / 46期
关键词：
MOF; 3D; zinc foam; anode; zinc-ion batteries; N-DOPED CARBON; HIGH-CAPACITY; ELECTROLYTES; ELECTRODES; COMPOSITE;
D O I：
10.1021/acsami.1c15794
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Rechargeable aqueous zinc-ion batteries (ZIBs) have been proven to be an alternative energy storage system because of their high safety, low cost, and eco-friendliness. However, the poor stability of metallic Zn anodes suffering from uncontrolled dendrite formation and electrochemical corrosion has brought troublesome hindrances for their practical application. In this work, we report a dual porous Zn-3D@600 anode prepared by coating a Zn@C protective layer on a 3D zinc skeleton. The Zn-3D@600 anode exhibits a highly stable and low polarization voltage during the Zn plating/stripping process and possesses a smooth and dendrite-free interface after long-term cycling. Moreover, the assembled Zn-3D@600 cell shows excellent cycle stability and superlative rate performance, delivering a discharge capacity of 198.8 mAh g(-1) after 1000 cycles at 1 A g(-1). Such excellent electrochemical performance can be credited to the Zn@C protective layer regulating uniform Zn nucleation and the 3D zinc skeleton accommodating Zn deposition at a high current density.
引用
收藏
页码：54990 / 54996
页数：7
相关论文
共 38 条
[1]   Enhanced reversible divalent zinc storage in a structurally stable α-MnO2 nanorod electrode [J].
Alfaruqi, Muhammad Hilmy ;
Gim, Jihyeon ;
Kim, Sungjin ;
Song, Jinju ;
Jo, Jeonggeun ;
Kim, Seokhun ;
Mathew, Vinod ;
Kim, Jaekook .
JOURNAL OF POWER SOURCES, 2015, 288 :320-327
[2]   Cationic Surfactant-Type Electrolyte Additive Enables Three-Dimensional Dendrite-Free Zinc Anode for Stable Zinc-Ion Batteries [J].
Bayaguud, Aruuhan ;
Luo, Xiao ;
Fu, Yanpeng ;
Zhu, Changbao .
ACS ENERGY LETTERS, 2020, 5 (09) :3012-3020
[3]   Single-Ion Conducting Double-Network Hydrogel Electrolytes for Long Cycling Zinc-Ion Batteries [J].
Chan, Cheuk Ying ;
Wang, Ziqi ;
Li, Yangling ;
Yu, Hui ;
Fei, Bin ;
Xin, John H. .
ACS APPLIED MATERIALS & INTERFACES, 2021, 13 (26) :30594-30602
[4]   Opportunities and challenges for a sustainable energy future [J].
Chu, Steven ;
Majumdar, Arun .
NATURE, 2012, 488 (7411) :294-303
[5]   Flexible and conductive scaffold-stabilized zinc metal anodes for ultralong-life zinc-ion batteries and zinc-ion hybrid capacitors [J].
Dong, Liubing ;
Yang, Wu ;
Yang, Wang ;
Tian, Hao ;
Huang, Yongfeng ;
Wang, Xianli ;
Xu, Chengjun ;
Wang, Chengyin ;
Kang, Feiyu ;
Wang, Guoxiu .
CHEMICAL ENGINEERING JOURNAL, 2020, 384
[6]   Electrodeposited Zinc-Based Films as Anodes for Aqueous Zinc Batteries [J].
Fayette, Matthew ;
Chang, Hee Jung ;
Rodriguez-Perez, Ismael A. ;
Li, Xiaolin ;
Reed, David .
ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (38) :42763-42772
[7]   Inorganic Colloidal Electrolyte for Highly Robust Zinc-Ion Batteries [J].
Gao, Jiawei ;
Xie, Xuesong ;
Liang, Shuquan ;
Lu, Bingan ;
Zhou, Jiang .
NANO-MICRO LETTERS, 2021, 13 (01)
[8]   Tailored Ni2P nanoparticles supported on N-doped carbon as a superior anode material for Li-ion batteries [J].
Guo, Huinan ;
Cai, Haichao ;
Li, Weiqin ;
Chen, Chengcheng ;
Chen, Kai ;
Zhang, Yan ;
Li, Yunwei ;
Wang, Mengying ;
Wang, Yijing .
INORGANIC CHEMISTRY FRONTIERS, 2019, 6 (07) :1881-1889
[9]   Multifunctional tin layer enabled long-life and stable anode for aqueous zinc-ion batteries [J].
Guo, W. ;
Zhang, Y. ;
Tong, X. ;
Wang, X. ;
Zhang, L. ;
Xia, X. ;
Tu, J. .
MATERIALS TODAY ENERGY, 2021, 20
[10]   PMMA-assisted Li deposition towards 3D continuous dendrite-free lithium anode [J].
Guo, Yanpeng ;
Ouyang, Yan ;
Li, Dian ;
Wei, Yaqing ;
Zhai, Tianyou ;
Li, Huiqiao .
ENERGY STORAGE MATERIALS, 2019, 16 :203-211
1234