Thermodynamic assessment of the Ga-Sn-Zn system

被引：6

作者：

Kulawik, Sebastian ^{[1
]}

Gierlotka, Wojciech ^{[2
]}

Debski, Adam ^{[3
]}

Gasior, Wladyslaw ^{[3
]}

Zajaczkowski, Andrzej ^{[1
]}

机构：

[1] Inst Nonferrous Met, Lukasiewicz Res Network, 5 Sowinskiego St, PL-44100 Gliwice, Poland

[2] Natl Dong Hwa Univ, Mat Sci & Engn Dept, Hualien, Taiwan

[3] Polish Acad Sci, Inst Met & Mat Sci, 25 Reymonta St, PL-30059 Krakow, Poland

来源：

CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY | 2020年 / 69卷

关键词：

Ga-Sn-Zn alloys; Mixing enthalpy; Calorimetry; Thermodynamic modelling; ZINC-TIN; SOLID SOLUBILITY; PHASE-EQUILIBRIA; STEAM TENSIONS; GALLIUM; CADMIUM; BINARY; ALLOYS; BISMUTH; LEAD;

D O I：

10.1016/j.calphad.2020.101765

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The integral molar mixing enthalpy of liquid ternary Ga-Sn-Zn alloys has been investigated using drop calorimetry method along five intersections as follows: X-Ga/X-Zn = 3/1 at 720 K, x(Ga)/x(Zn) = 1/1 at 718 K and 720 K, x(Ga)/x(Zn) = 1/3 at 718 K, x(Ga)/x(Sn) = 3/17 at 718 K and for x(Ga)/x(Sn) = 1/3 at 720 K. Based on obtained thermodynamic results and those available in the literature the thermodynamic optimization was done using Thermo-Calc software. Next, the phase equilibria in the binary and ternary systems were calculated and the results were compared with those obtained using different experimental techniques.

引用

页数：16

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