Compressed atoms

被引:149
作者
Buchachenko, AL [1 ]
机构
[1] Russian Acad Sci, Inst Chem Phys, Moscow 117334, Russia
关键词
D O I
10.1021/jp003852u
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Many atomic systems exhibit indications of compressed electronic shell: atoms locked in crystals, solids at cryogenic temperatures, atoms trapped by fullerene cages, and atoms in substances under high pressure. This paper collects available experimental data on the ESR, NMR, and magnetic moments of compressed atoms and formulates some general trends in the behavior of magnetic parameters displayed by compressed atoms. The paper lays special emphasis on the electron-nuclear (hyperfine) coupling as a parameter characterizing the modification of atomic orbitals and the redistribution of; spin density in atoms under compression.
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页码:5839 / 5846
页数:8
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