Imprinting macropore arrays into mesoporous silica monoliths

被引:7
|
作者
Grimm, Silko [1 ,2 ]
Lange, Andreas [3 ]
Enke, Dirk [3 ]
Steinhart, Martin [1 ]
机构
[1] Univ Osnabruck, Inst Chem, D-46069 Osnabruck, Germany
[2] Max Planck Inst Mikrostrukturphys, D-06120 Halle, Germany
[3] Univ Leipzig, Inst Tech Chem, D-04103 Leipzig, Germany
关键词
ANODIC POROUS ALUMINA; METAL NANOHOLE ARRAYS; HIGH ASPECT RATIOS; MICROPILLAR ARRAYS; 2-STEP REPLICATION; PORE STRUCTURE; FABRICATION; SYSTEM; FORCE; GEL;
D O I
10.1039/c2jm31245j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Mesoporous silica monoliths containing arrays of aligned macropores oriented perpendicular to their surfaces were prepared by non-destructive imprinting of sol/gels with polymer nanorod arrays. Crack-free monoliths with areas of up to 2.5 cm(2) were obtained by a combination of slow drying under ambient conditions and optimized freeze-drying.
引用
收藏
页码:9490 / 9493
页数:4
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