Synthesis of the novel MOF hcp UiO-66 employing ionic liquids as a linker precursor

被引：50

作者：

Ermer, Matthias ^{[1
]}

Mehler, Julian ^{[2
]}

Kriesten, Martin ^{[1
]}

Avadhut, Yamini S. ^{[1
]}

Schulz, Peter S. ^{[2
]}

Hartmann, Martin ^{[1
]}

机构：

[1] Friedrich Alexander Univ Erlangen Nurnberg FAU, ECRC, Egerlandstr 3, D-91058 Erlangen, Germany

[2] Friedrich Alexander Univ Erlangen Nurnberg FAU, Inst Chem React Engn, Egerlandstr 3, D-91058 Erlangen, Germany

来源：

DALTON TRANSACTIONS | 2018年 / 47卷 / 41期

关键词：

METAL-ORGANIC FRAMEWORKS; IONOTHERMAL SYNTHESIS; MODULATED SYNTHESIS; ADSORPTION; MIXTURES; ROUTES; ZR;

D O I：

10.1039/c8dt02999g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By using a terephthalate containing ionic liquid, a new metal-organic framework, hcp UiO-66, comprising (Zr12O8(OH)(14)) double clusters and terephthalate ligands has been synthesized. The hydrothermal synthesis of hcp UiO-66 might help to establish metal-organic frameworks for industrial scale applications.

引用

收藏

页码：14426 / 14430

页数：5

相关论文

共 33 条

[1] A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability [J].

Cavka, Jasmina Hafizovic ;

Jakobsen, Soren ;

Olsbye, Unni ;

Guillou, Nathalie ;

Lamberti, Carlo ;

Bordiga, Silvia ;

Lillerud, Karl Petter .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (42) :13850-13851

[2] H2 storage in isostructural UiO-67 and UiO-66 MOFs [J].

Chavan, Sachin ;

Vitillo, Jenny G. ;

Gianolio, Diego ;

Zavorotynska, Olena ;

Civalleri, Bartolomeo ;

Jakobsen, Soren ;

Nilsen, Merete H. ;

Valenzano, Loredana ;

Lamberti, Carlo ;

Lillerud, Karl Petter ;

Bordiga, Silvia .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (05) :1614-1626

[3] Metal-Organic Nanosheets Formed via Defect-Mediated Transformation of a Hafnium Metal-Organic Framework [J].

Cliffe, Matthew J. ;

Castillo-Martinez, Elizabeth ;

Wu, Yue ;

Lee, Jeongjae ;

Forse, Alexander C. ;

Firth, Francesca C. N. ;

Moghadam, Peyman Z. ;

Fairen-Jimenez, David ;

Gaultois, Michael W. ;

Hill, Joshua A. ;

Magdysyuk, Oxana V. ;

Slater, Ben ;

Goodwin, Andrew L. ;

Grey, Clare P. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (15) :5397-5404

[4] Ionic liquids and eutectic mixtures as solvent and template in synthesis of zeolite analogues [J].

Cooper, ER ;

Andrews, CD ;

Wheatley, PS ;

Webb, PB ;

Wormald, P ;

Morris, RE .

NATURE, 2004, 430 (7003) :1012-1016

[5] Electron Crystallography Reveals Atomic Structures of Metal-Organic Nanoplates with M12(μ3-O)8(μ3-OH)8(μ2-OH)6 (M = Zr, Hf) Secondary Building Units [J].

Dai, Ruihan ;

Peng, Fei ;

Ji, Pengfei ;

Lu, Kuangda ;

Wang, Cheng ;

Sun, Junhang ;

Lin, Wenbin .

INORGANIC CHEMISTRY, 2017, 56 (14) :8128-8134

[6] Direct synthesis of non-breathing MIL-53(Al)(ht) from a terephthalate-based ionic liquid as linker precursor [J].

Fischer, Marcus ;

Schwegler, Johannes ;

Paula, Carolin ;

Schulz, Peter S. ;

Hartmann, Martin .

DALTON TRANSACTIONS, 2016, 45 (46) :18443-18446

[7] Ionic Liquids and Poly(ionic liquid)s for Morphosynthesis of Inorganic Materials [J].

Gao, Min-Rui ;

Yuan, Jiayin ;

Antonietti, Markus .

CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (23) :5391-5403

[8] Life-cycle assessment as a tool for eco-design of metal-organic frameworks (MOFs) [J].

Grande, Carlos A. ;

Blom, Richard ;

Spjelkavik, Aud ;

Moreau, Valentine ;

Payet, Jerome .

SUSTAINABLE MATERIALS AND TECHNOLOGIES, 2017, 14 :11-18

[9] Pore size determination in modified micro- and mesoporous materials.: Pitfalls and limitations in gas adsorption data analysis [J].

Groen, JC ;

Peffer, LAA ;

Pérez-Ramírez, J .

MICROPOROUS AND MESOPOROUS MATERIALS, 2003, 60 (1-3) :1-17

[10] A zirconium methacrylate oxocluster as precursor for the low-temperature synthesis of porous zirconium(IV) dicarboxylates [J].

Guillerm, Vincent ;

Gross, Silvia ;

Serre, Christian ;

Devic, Thomas ;

Bauer, Matthias ;

Ferey, Gerard .

CHEMICAL COMMUNICATIONS, 2010, 46 (05) :767-769

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