Copper(II) complexes bearing cyclobutanecarboxylate and pyridine ligands: a new series of dinuclear paddle-wheel complexes

被引:6
作者
Edelsbacher, Philipp [1 ]
Hammer, Gunther Red [2 ]
Monkowius, Uwe [1 ]
机构
[1] Johannes Kepler Univ Linz, Sch Educ, Altenbergerstr 69, Linz 4040, Austria
[2] Paris Lodron Univ Salzburg, Chem & Phys Mat, Abt Materialwissensch & Mineral, Jakob Haringerstr 2A, Salzburg 5020, Austria
来源
MONATSHEFTE FUR CHEMIE | 2020年 / 151卷 / 04期
关键词
Copper(II) complexes; Paddle-wheel structure; Crystal structure; CARBOXYLATES;
D O I
10.1007/s00706-020-02589-3
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Four members of a new series of paddle-wheel copper(II) complexes bearing cyclobutanecarboxylate as bridging ligand with pyridine derived ligands in axial positions are reported. They have been characterised by FTIR-ATR, UV-Vis spectroscopy, mass spectrometry, and single crystal X-ray diffraction. The synthesis is straight-forward by combining the carboxylic acid, copper(II) acetate, and a slight excess of a pyridine ligand. The molecular structures of three complexes reveal a coordination mode expected for such type of dinuclear copper(II) carboxylates. [GRAPHICS] .
引用
收藏
页码:543 / 547
页数:5
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