Gas sensors based on ultrathin porous Co3O4 nanosheets to detect acetone at low temperature

被引:100
作者
Zhang, Ziyue [1 ,2 ]
Wen, Zhen [1 ,2 ]
Ye, Zhizhen [1 ,2 ]
Zhu, Liping [1 ,2 ]
机构
[1] Zhejiang Univ, Sch Mat Sci & Engn, Hangzhou, Zhejiang, Peoples R China
[2] State Key Lab Silicon Mat, Hangzhou 310027, Zhejiang, Peoples R China
关键词
VOLATILE ORGANIC-COMPOUNDS; BREATH ANALYSIS; SENSING PROPERTIES; NANOROD ARRAYS; LUNG-CANCER; NANOCRYSTALS;
D O I
10.1039/c5ra08536e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Using a facile two-step process, including a hydrothermal technique and subsequently controlled annealing of the precursor, ultrathin porous Co3O4 nanosheets can be synthesized. The gas sensor based on the porous Co3O4 nanosheets shows a superior acetone gas-sensing performance at a low operating temperature of 150 degrees C. The gas response to 100 ppm acetone reached 11.4, and exhibited good reproducibility. In addition, the detection limit of the Co3O4 nanosheet sensor is lower than 1.8 ppm, which is the diagnostic criteria exhaled from diabetes. What's more, the sensor exhibited good stability when tested over 2 months. The outstanding gas-sensing properties were explained by a typical p-type semiconductor behavior with an ultrathin porosity structure as well as a large specific surface area of Co3O4 nanosheets.
引用
收藏
页码:59976 / 59982
页数:7
相关论文
共 35 条
[1]   NO and NO2 Sensing Properties of WO3 and Co3O4 Based Gas Sensors [J].
Akamatsu, Takafumi ;
Itoh, Toshio ;
Izu, Noriya ;
Shin, Woosuck .
SENSORS, 2013, 13 (09) :12467-12481
[3]   C2H5OH sensing characteristics of various Co3O4 nanostructures prepared by solvothermal reaction [J].
Choi, Kwon-Il ;
Kim, Hae-Ryong ;
Kim, Kang-Min ;
Li, Dawei ;
Cao, Guozhong ;
Lee, Jong-Heun .
SENSORS AND ACTUATORS B-CHEMICAL, 2010, 146 (01) :183-189
[4]   Olfactory systems for medical applications [J].
D'Amico, A. ;
Di Natale, C. ;
Paolesse, R. ;
Macagnano, A. ;
Martinelli, E. ;
Pennazza, G. ;
Santonico, A. ;
Bernabei, M. ;
Roscioni, C. ;
Galluccio, G. ;
Bono, R. ;
Finazzi Agro, E. ;
Rullo, S. .
SENSORS AND ACTUATORS B-CHEMICAL, 2008, 130 (01) :458-465
[5]   Electrospun nanomaterials for ultrasensitive sensors [J].
Ding, Bin ;
Wang, Moran ;
Wang, Xianfeng ;
Yu, Jianyong ;
Sun, Gang .
MATERIALS TODAY, 2010, 13 (11) :16-27
[6]   Accurate, reproducible measurement of acetone concentration in breath using selected ion flow tube-mass spectrometry [J].
Dummer, Jack F. ;
Storer, Malina K. ;
Hu, Wan-Ping ;
Swanney, Maureen P. ;
Milne, Gordon J. ;
Frampton, Christopher M. ;
Scotter, Jenny M. ;
Prisk, G. Kim ;
Epton, Michael J. .
JOURNAL OF BREATH RESEARCH, 2010, 4 (04)
[7]   Metal Oxide Semi-Conductor Gas Sensors in Environmental Monitoring [J].
Fine, George F. ;
Cavanagh, Leon M. ;
Afonja, Ayo ;
Binions, Russell .
SENSORS, 2010, 10 (06) :5469-5502
[8]   A Novel Breath Analysis System Based on Electronic Olfaction [J].
Guo, Dongmin ;
Zhang, David ;
Li, Naimin ;
Zhang, Lei ;
Yang, Jianhua .
IEEE TRANSACTIONS ON BIOMEDICAL ENGINEERING, 2010, 57 (11) :2753-2763
[9]   Assessment, origin, and implementation of breath volatile cancer markers [J].
Haick, Hossam ;
Broza, Yoav Y. ;
Mochalski, Pawel ;
Ruzsanyi, Vera ;
Amann, Anton .
CHEMICAL SOCIETY REVIEWS, 2014, 43 (05) :1423-1449
[10]   Volatile Organic Compounds of Lung Cancer and Possible Biochemical Pathways [J].
Hakim, Meggie ;
Broza, Yoav Y. ;
Barash, Orna ;
Peled, Nir ;
Phillips, Michael ;
Amann, Anton ;
Haick, Hossam .
CHEMICAL REVIEWS, 2012, 112 (11) :5949-5966