Structure and magnetic properties of Sm2Rh3Sn5 - an intergrowth of TiNiSi- and NdRh2Sn4-related slabs

被引：5
|
作者：
Heying, Birgit [1 ]
Koesters, Jutta [1 ]
Hoffmann, Rolf-Dieter [1 ]
Heletta, Lukas [1 ]
Poettgen, Rainer [1 ]
机构：
[1] Univ Munster, Inst Anorgan & Analyt Chem, Corrensstr 30, D-48149 Munster, Germany
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2017年 / 72卷 / 10期
关键词：
intermetallics; magnetic properties; samarium; stannide; INTERMETALLIC COMPOUNDS; TERNARY STANNIDES; RE; SM; SUPERCONDUCTIVITY; SILICIDES; TRANSPORT; SEGMENTS; RHODIUM; PR;
D O I：
10.1515/znb-2017-0127
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The stannide Sm2Rh3Sn5 was obtained by arcmelting of the elements and subsequent annealing at 1070 K in a silica tube. Sm2Rh3Sn5 crystallizes with the orthorhombic Y2Rh3Sn5 type structure, space group Cmc2(1), Z = 4: a = 444.46(8), b = 2636.2(4), c = 718.3(1) pm, wR = 0.0711, 1761 F-2 values and 61 variables. The three crystallographically independent rhodium atoms show tricapped trigonal prismatic coordination by samarium and tin atoms. Sm2Rh3Sn5 can be considered as a simple 1:1 intergrowth structure of TiNiSi- and NdRh2Sn4-related slabs of compositions SmRhSn and SmRh2Sn4. Temperature dependent magnetic susceptibility data revealed van Vleck type behavior caused by the proximity of the exited H-6(7/2) state to the H-6(5/2) ground state of Sm3+, and an antifer-romagnetic ordering occurs at T-N = 3.5(5)K.
引用
收藏
页码：753 / 758
页数：6
相关论文
共 50 条
  • [21] Synthesis, structure characterization and magnetic properties of tellurostannates [M(en)3]2(Sn2Te6) (M = Mn, Zn)
    Li, J
    Chen, Z
    Emge, TJ
    Yuen, T
    Proserpio, DM
    INORGANICA CHIMICA ACTA, 1998, 273 (1-2) : 310 - 315
  • [22] Crystal structure, chemical bonding and magnetic properties of the new antimonides Ce2Ir3Sb4, La2Ir3Sb4, and Ce2Rh3Sb4
    Cardoso-Gil, Raul
    Caroca-Canales, Nubia
    Budnyk, Serhiy
    Schnelle, Walter
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS, 2011, 226 (08): : 657 - 666
  • [23] Transport and Magnetic Properties of R2Ir3Sn5 (R = La, Ce, Pr, and Nd) System
    Sangeetha, N. S.
    Thamizhavel, A.
    Basu, Saurabh
    Ramakrishnan, S.
    Pal, D.
    SOLID STATE PHYSICS: PROCEEDINGS OF THE 55TH DAE SOLID STATE PHYSICS SYMPOSIUM 2010, PTS A AND B, 2011, 1349 : 1215 - +
  • [24] Atomically precise rhodium nanoclusters: synthesis and characterization of the heterometallic [Rh18Sn3Cl2(CO)33]4- and [Rh7Sn4Cl10(CO)14]5- carbonyl compounds
    Bussoli, Guido
    Cesari, Cristiana
    Femoni, Cristina
    Iapalucci, Maria Carmela
    Ruggieri, Silvia
    Tiozzo, Cristina
    Zacchini, Stefano
    RESULTS IN CHEMISTRY, 2022, 4
  • [25] Structural and magnetic properties of REMn6Sn≈4Ge≈2 compounds (RE = Sc, Y, Nd, Sm, Gd-Tm, Lu)
    Venturini, G
    JOURNAL OF ALLOYS AND COMPOUNDS, 2005, 398 (1-2) : 42 - 47
  • [26] Crystal Growth and Magnetic Properties of Pr3Co2+xGe7 and the Sn-Stabilized Ln3Co2+xGe7-ySny (Ln = Pr, Nd, Sm)
    Khan, Mojammel A.
    McCandless, Gregory T.
    Benavides, Katherine A.
    Martin, Thomas J.
    Palacios, Adzuira M.
    Samuel, Anthony W. B.
    Young, David P.
    Chan, Julia Y.
    CRYSTAL GROWTH & DESIGN, 2018, 18 (10) : 6028 - 6034
  • [27] Electrical and magnetic properties of the Sn4+ substituted spinel ferrite, ZnSnxFe2-4x/3O4 (0.00≤x≤0.30)
    Lee, JY
    Lee, GJ
    Kim, HS
    Lee, SH
    Lee, DH
    Yo, CH
    Kim, KH
    Ahn, K
    MATERIALS CHEMISTRY AND PHYSICS, 1998, 52 (03) : 267 - 271
  • [28] Pt5Mn2Si, the first platinum-rich ternary intermetallic of the Rh5Ge3 structure type: Synthesis, crystal and electronic structure, and magnetic properties
    Makhaneva, Anastasiya Yu.
    Zakharova, Elena Yu.
    Nesterenko, Sergey N.
    Kazakov, Sergey M.
    Lyssenko, Konstantin A.
    Efimov, Nikolay N.
    Kuznetsov, Alexey N.
    INTERMETALLICS, 2024, 164
  • [29] Crystal growth, structure and magnetic properties of Sm3Ni5Al19: A compound in the Sm2n+mNi4n+mAl15n+4m homologous series
    UDUMULA SUBBARAO
    ALOKE KUMAR GHOSH
    SUMANTA SARKAR
    SEBASTIAN C PETER
    Journal of Chemical Sciences, 2014, 126 : 1605 - 1613
  • [30] Electronic structure, magnetic and thermal properties of Rh2MnZ (Z=Ge, Sn, Pb) compounds under pressure from ab-initio quasi-harmonic method
    Benkhelifa, F. Z.
    Lekhal, A.
    Mecabih, S.
    Abbar, B.
    Bouhafs, B.
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2014, 371 : 130 - 134
12345