N-Heterocyclic carbenes versus transition metals for stabilizing phosphinyl radicals

被引：96

作者：

Back, Olivier ^{[1
]}

Donnadieu, Bruno ^{[1
]}

von Hopffgarten, Moritz ^{[2
]}

Klein, Susanne ^{[2
]}

Tonner, Ralf ^{[2
]}

Frenking, Gernot ^{[2
]}

Bertrand, Guy ^{[1
]}

机构：

[1] Univ Calif Riverside, Dept Chem, Joint Res Chem Lab UMI 2957, Riverside, CA 92521 USA

[2] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany

来源：

CHEMICAL SCIENCE | 2011年 / 2卷 / 05期

基金：

美国国家科学基金会;

关键词：

ELECTRON-SPIN-RESONANCE; MAIN-GROUP ELEMENTS; PARAMAGNETIC-RESONANCE; PHOSPHORUS; COMPLEXES; PERSISTENT; LIGANDS; CATION; METATHESIS; GENERATION;

D O I：

10.1039/c1sc00027f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It is shown that vanadium-iminato ligands are more efficient than imidazolidin-2-iminato substituents to delocalize the spin density from a phosphorus nucleus. However, the latter is stabilizing enough to allow for the isolation and characterization in the liquid and solid states of a neutral phosphinyl radical.

引用

页码：858 / 861

页数：4

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