Novel C60-anchored two-armed poly(tert-butyl acrylate):: Synthesis and characterization

被引：16
|
作者：
Chu, CC
Wang, LY [1 ]
Ho, TI
机构：
[1] Natl Taiwan Univ, Ctr Condensed Matter Sci, Taipei 10617, Taiwan
[2] Natl Taiwan Univ, Dept Chem, Taipei 10617, Taiwan
[3] Natl Taiwan Univ, Inst Polymer Sci & Engn, Taipei 10617, Taiwan
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2005年 / 26卷 / 14期
关键词：
atom transfer radical polymerization (ATRP); fullerenes; poly(tert-butyl acrylate) (PtBA); telechelics; water-soluble polymers;
D O I：
10.1002/marc.200500192
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A multistep synthetic procedure for preparing novel C-60-anchored two-armed poly(tert-butyl acrylate) was developed. First, two-armed poly(tert-butyl acrylate) bearing a malonate ester core with well-controlled molecular weight was synthesized through atom transfer radical polymerization. The effective Bingel reaction between C-60 and the well-defined polymer was then carried out to yield C60-anchored polymer. GPC, H-1 NMR, and UV-vis spectroscopy indicated that the C60-anchored polymer was a monosubstituted and 'closed' 6,6-ring-bridged methanofullerene derivative.
引用
收藏
页码：1179 / 1184
页数：6
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