Lead-free mesoscopic Cs2SnI6 perovskite solar cells using different nanostructured ZnO nanorods as electron transport layers

被引:161
作者
Qiu, Xiaofeng [1 ]
Jiang, Yanan [1 ]
Zhang, Hailiang [1 ]
Qiu, Zhiwen [1 ]
Yuan, Shuai [1 ]
Wang, Ping [1 ]
Cao, Bingqiang [1 ]
机构
[1] Univ Jinan, Sch Mat Sci & Engn, Mat Res Ctr Photoelect & Photoelectrochem Energy, Jinan 250022, Peoples R China
来源
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS | 2016年 / 10卷 / 08期
关键词
perovskite; absorbers; air-stable; lead-free; Cs2SnI6; mesoscopic solar cells; PULSED-LASER DEPOSITION; TIO2 NANOWIRE ARRAYS; CH3NH3PBI3; PEROVSKITE; EFFICIENCY; FILMS; PERFORMANCE; SENSITIZER; GROWTH;
D O I
10.1002/pssr.201600166
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Lead-free and more air-stable perovskite Cs2SnI6 absorber with a direct bandgap of 1.48 eV is synthesized via a modified solution process. Different nanostructured ZnO nanorod arrays as electron transport layers and hole blocking layers are grown by controlling the seed layer and used to fabricate mesoscopic perovskite solar cells with Cs2SnI6 as light absorber layer. The influences of ZnO seed layers and nanorod morphology on the device photovoltaic performance were also investigated. With careful control of ZnO nanorod length and pore size to ensure high loading of the Cs2SnI6 absorber, we achieved power conversion efficiency of near 1%. (C) 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
引用
收藏
页码:587 / 591
页数:5
相关论文
共 30 条
[1]   Efficient and stable CH3NH3PbI3-sensitized ZnO nanorod array solid-state solar cells [J].
Bi, Dongqin ;
Boschloo, Gerrit ;
Schwarzmueller, Stefan ;
Yang, Lei ;
Johansson, Erik M. J. ;
Hagfeldt, Anders .
NANOSCALE, 2013, 5 (23) :11686-11691
[2]   Solid state plasmonic dye sensitized solar cells based on solution processed perovskite CsSnI3 as the hole transporter [J].
Chander, N. ;
Chandrasekhar, P. S. ;
Komarala, V. K. .
RSC ADVANCES, 2014, 4 (98) :55658-55665
[3]   High efficiency electrospun TiO2 nanofiber based hybrid organic-inorganic perovskite solar cell [J].
Dharani, Sabba ;
Mulmudi, Hemant Kumar ;
Yantara, Natalia ;
Pham Thi Thu Trang ;
Park, Nam Gyu ;
Graetzel, Michael ;
Mhaisalkar, Subodh ;
Mathews, Nripan ;
Boix, Pablo P. .
NANOSCALE, 2014, 6 (03) :1675-1679
[4]   Vertically Aligned Single Crystal TiO2 Nanowire Arrays Grown Directly on Transparent Conducting Oxide Coated Glass: Synthesis Details and Applications [J].
Feng, Xinjian ;
Shankar, Karthik ;
Varghese, Oomman K. ;
Paulose, Maggie ;
Latempa, Thomas J. ;
Grimes, Craig A. .
NANO LETTERS, 2008, 8 (11) :3781-3786
[5]   Lead-free solid-state organic-inorganic halide perovskite solar cells [J].
Hao, Feng ;
Stoumpos, Constantinos C. ;
Duyen Hanh Cao ;
Chang, Robert P. H. ;
Kanatzidis, Mercouri G. .
NATURE PHOTONICS, 2014, 8 (06) :489-494
[6]   Local field effects on electron transport in nanostructured TiO2 revealed by terahertz spectroscopy [J].
Hendry, E ;
Koeberg, M ;
O'Regan, B ;
Bonn, M .
NANO LETTERS, 2006, 6 (04) :755-759
[7]   Humidity controlled crystallization of thin CH3NH3PbI3 films for high performance perovskite solar cell [J].
Jeong, Beomjin ;
Cho, Suk Man ;
Cho, Sung Hwan ;
Lee, Ju Han ;
Hwang, Ihn ;
Hwang, Sun Kak ;
Cho, Jinhan ;
Lee, Tae-Woo ;
Park, Cheolmin .
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS, 2016, 10 (05) :381-387
[8]   High Efficiency Solid-State Sensitized Solar Cell-Based on Submicrometer Rutile TiO2 Nanorod and CH3NH3PbI3 Perovskite Sensitizer [J].
Kim, Hui-Seon ;
Lee, Jin-Wook ;
Yantara, Natalia ;
Boix, Pablo P. ;
Kulkarni, Sneha A. ;
Mhaisalkar, Subodh ;
Graetzel, Michael ;
Park, Nam-Gyu .
NANO LETTERS, 2013, 13 (06) :2412-2417
[9]   Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9% [J].
Kim, Hui-Seon ;
Lee, Chang-Ryul ;
Im, Jeong-Hyeok ;
Lee, Ki-Beom ;
Moehl, Thomas ;
Marchioro, Arianna ;
Moon, Soo-Jin ;
Humphry-Baker, Robin ;
Yum, Jun-Ho ;
Moser, Jacques E. ;
Graetzel, Michael ;
Park, Nam-Gyu .
SCIENTIFIC REPORTS, 2012, 2
[10]   Lead-Free Halide Perovskite Solar Cells with High Photocurrents Realized Through Vacancy Modulation [J].
Kumar, Mulmudi Hemant ;
Dharani, Sabba ;
Leong, Wei Lin ;
Boix, Pablo P. ;
Prabhakar, Rajiv Ramanujam ;
Baikie, Tom ;
Shi, Chen ;
Ding, Hong ;
Ramesh, Ramamoorthy ;
Asta, Mark ;
Graetzel, Michael ;
Mhaisalkar, Subodh G. ;
Mathews, Nripan .
ADVANCED MATERIALS, 2014, 26 (41) :7122-+