A mild and highly chemoselective iodination of alcohol using polymer supported DMAP

被引：9
作者：
Das, Diparjun [1 ]
Anal, Jasha Momo H. [2 ]
Rokhum, Lalthazuala [1 ]
机构：
[1] Natl Inst Technol, Dept Chem, Silchar 788010, Assam, India
[2] North Eastern Hill Univ, Dept Chem, Shillong 793022, Meghalaya, India
来源：
JOURNAL OF CHEMICAL SCIENCES | 2016年 / 128卷 / 11期
关键词：
Iodination; Polymer supported DMAP; Triphenylphosphine; Iodine; Catalyst; Chemoselective; SOLVENT-FREE CONDITIONS; CBZ-PROTECTION; REAGENT SYSTEM; ALKYL-HALIDES; HYDROXY-GROUP; IODO-GROUP; EFFICIENT; CATALYSTS; TRIPHENYLPHOSPHINE/IODINE; CONFIGURATION;
D O I：
10.1007/s12039-016-1158-1
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis of organic compounds using polymer supported catalysts and reagents, where the required product is always in solution, has been of great interest in recent years, both in industries and academia especially in pharmaceutical research. Here, a simple and efficient method for conversion of alcohols into their iodides in high yield using polymer supported 4-(Dimethylamino)pyridine (DMAP) is described. Polymer supported DMAP is used in catalytic amount and is recovered and reused several times. Additionally, this method is highly chemoselective.
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页码：1695 / 1701
页数：7
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