IR Microscopy as a Method for Studying the Influence of An External Electric Field on the Spin Crossover Exemplified by the Fe(II) Complex with 2,6-Bis(pyrazol-1-yl)pyridine

被引：3

作者：

Minakova, O. V. ^{[1
,2
]}

Tumanov, S. V. ^{[1
,2
]}

Fedin, M. V. ^{[1
,2
]}

Veber, S. L. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Siberian Branch, Int Tomog Ctr, Novosibirsk, Russia

[2] Novosibirsk State Univ, Novosibirsk, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2020年 / 46卷 / 05期

基金：

俄罗斯科学基金会;

关键词：

coordination compounds; spin crossover; iron(II); FT-IR microscopy;

D O I：

10.1134/S1070328420040041

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The influence of the electric field on the spin state of the single crystal of [Fe(1-Bpp)(2)][BF4](2) demonstrating the spin crossover phenomenon is studied. The spin state of the complex is determined by the indirect method: FT-IR microscopy. The experimental results show that the application of the external electrostatic field with an intensity of 13 kV/cm exerts no effect on the temperature of the magnetostructural transition of the compound within 0.2 K.

引用

页码：326 / 329

页数：4

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