In flow-based technologies: A new paradigm for the synthesis and processing of covalent-organic frameworks

被引：24

作者：

Martinez-Bulit, Pablo ^{[1
]}

Sorrenti, Alessandro ^{[1
,2
]}

Miguel, David Rodriguez San ^{[1
]}

Mattera, Michele ^{[1
]}

Belce, Yonca ^{[1
]}

Xia, Yanming ^{[3
]}

Ma, Shenglin ^{[3
]}

Huang, Mu-Hua ^{[4
]}

Pane, Salvador ^{[5
]}

Puigmarti-Luis, Josep ^{[1
,6
]}

机构：

[1] Univ Barcelona UB, Inst Quim Teor & Computac, Dept Ciencia Mat & Quim Fis, Barcelona 08028, Spain

[2] Univ Barcelona UB, Inst Quim Inorgan & Organ, Barcelona 08028, Spain

[3] Xiamen Univ, Dept Mech & Elect Engn, Xiamen 361005, Peoples R China

[4] Beijing Inst Technol, Sch Mat Sci & Engn, Expt Ctr Adv Mat, 5 Zhongguancun South St, Beijing 100081, Peoples R China

[5] Swiss Fed Inst Technol, Multiscale Robot Lab, Tannenstr 3, CH-8092 Zurich, Switzerland

[6] Inst Catalana Recerca & Estudis Avancats ICREA, Pg Lluis Co 23, Barcelona 08010, Spain

来源：

CHEMICAL ENGINEERING JOURNAL | 2022年 / 435卷

基金：

瑞士国家科学基金会; 欧洲研究理事会;

关键词：

Microfluidic technologies; Crystallization; Covalent-organic frameworks; Reaction-diffusion mixing; Simulated microgravity; PROTEIN CRYSTAL-GROWTH; MICROFLUIDIC APPROACH; CRYSTALLIZATION; MICROGRAVITY; NUCLEATION; FIBERS; CHIP;

D O I：

10.1016/j.cej.2022.135117

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Nearly twenty years since the discovery of covalent-organic frameworks (COFs), most of the research on these materials has been focused on the rational design of new structures. Recently, the quest for discovering the functionalities and potential applications of these crystalline materials has attracted the attention of many researchers. While the number of reports regarding these two aspects within the COF research area is continuously growing, in order to achieve their full potential, the processability aspect of COFs also needs to be addressed. In this review article, we examine the opportunities that flow-based technologies offer regarding (a) the continuous synthesis of COFs, and (b) the processing of these materials into functional surfaces and devices (e.g. thin films and 3D structures), both aspects being ultimately amenable to industrial scale up.

引用

页数：10

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