Monomeric phosphinoboranes

被引：35

作者：

Bailey, Jonathan A. ^{[1
]}

Pringle, Paul G. ^{[1
]}

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

COORDINATION CHEMISTRY REVIEWS | 2015年 / 297卷

关键词：

Phosphorus; Boron; Phosphinoboranes; Borylphosphines; Ligand synthesis; Homogeneous catalysis; COORDINATION CHEMISTRY; CONJUGATE BASE; B-N; CRYSTAL-STRUCTURES; AMMONIA-BORANE; P-B; BORON; BONDS; BORYLPHOSPHINE; NAPHTHALENE;

D O I：

10.1016/j.ccr.2015.02.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The key developments in the chemistry of R2PBR'(2) over the last 20 years are reviewed. The categorization of phosphinoboranes as R2P=BW'(2) species and borylphosphines as R2P-BR'(2) species is suggested based on an analysis of the literature X-ray crystal structures. The chemistry of derivatives of the simplest borylphosphine H2P-BH2 is discussed. Six methods of preparation of R2PBR'(2) are presented along with the reactions of the products with H-2, amine-boranes, elemental chalcogens, Me3NO and compounds featuring C=O, C=C and C N functionalities. The two modes of coordination of R2PBR'(2) to transition metals, kappa(1) (P) and eta(2) (P=B), are covered, along with the applications of borylphosphine complexes in homogeneous catalysis. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：77 / 90

页数：14

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