The relationship between liquid, supercooled and glassy water

被引:1666
作者
Mishima, O
Stanley, HE
机构
[1] Natl Inst Res Inorgan Mat, Tsukuba, Ibaraki 3050044, Japan
[2] Japan Sci & Technol Corp, Core Res Evolut Sci & Technol, Tokyo, Japan
[3] Boston Univ, Ctr Polymer Studies, Boston, MA 02215 USA
[4] Boston Univ, Dept Phys, Boston, MA 02215 USA
关键词
D O I
10.1038/24540
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
That water can exist in two distinct 'glassy' forms-low- and high-density amorphous Ice-may provide the key to understanding some of the puzzling characteristics of cold and supercooled water, of which the glassy solids are more-viscous counterparts. Recent experimental and theoretical studies of both liquid and glassy water are now starting to offer the prospect of a coherent picture of the unusual properties of this ubiquitous substance.
引用
收藏
页码:329 / 335
页数:7
相关论文
共 100 条
[1]   DENSITY-DRIVEN LIQUID-LIQUID PHASE-SEPARATION IN THE SYSTEM AL2O3-Y2O3 [J].
AASLAND, S ;
MCMILLAN, PF .
NATURE, 1994, 369 (6482) :633-636
[2]  
Angell C.A., 1982, WATER COMPREHENSIVE, V7, P1, DOI DOI 10.1007/978-1-4757-6952-4
[3]   GLASS-FORMING COMPOSITION REGIONS AND GLASS TRANSITION TEMPERATURES FOR AQUEOUS ELECTROLYTE SOLUTIONS [J].
ANGELL, CA ;
SARE, EI .
JOURNAL OF CHEMICAL PHYSICS, 1970, 52 (03) :1058-&
[4]   ANOMALOUS PROPERTIES OF SUPERCOOLED WATER - HEAT-CAPACITY, EXPANSIVITY, AND PROTON MAGNETIC-RESONANCE CHEMICAL-SHIFT FROM 0 TO -38 DEGREES [J].
ANGELL, CA ;
SHUPPERT, J ;
TUCKER, JC .
JOURNAL OF PHYSICAL CHEMISTRY, 1973, 77 (26) :3092-3099
[5]  
Angell CA, 1996, J NON-CRYST SOLIDS, V207, P463, DOI 10.1016/S0022-3093(96)00261-X
[6]   Landscapes with megabasins: Polyamorphism in liquids and biopolymers and the role of nucleation in folding and folding diseases [J].
Angell, CA .
PHYSICA D-NONLINEAR PHENOMENA, 1997, 107 (2-4) :122-142
[7]  
[Anonymous], 2021, METASTABLE LIQUIDS
[8]  
[Anonymous], HYDROGEN BONDING, DOI DOI 10.1016/B978-0-08-009140-2.50004-X
[9]   SUPERCOOLING OF WATER BELOW THE ANOMALOUS RANGE NEAR 226 K [J].
BARTELL, LS ;
HUANG, JF .
JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (31) :7455-7457
[10]   Is there a liquid-liquid phase transition in supercooled water? [J].
Bellissent-Funel, MC .
EUROPHYSICS LETTERS, 1998, 42 (02) :161-166