A large pyrene-fused N-heteroacene: fifteen aromatic six- membered rings annulated in one row

被引：118

作者：

Wang, Zilong ^{[1
]}

Gu, Peiyang ^{[1
]}

Liu, Guangfeng ^{[1
]}

Yao, Huiying ^{[2
]}

Wu, Yishi ^{[3
]}

Li, Yongxin ^{[4
]}

Rakesh, Ganguly ^{[4
]}

Zhu, Jia ^{[2
]}

Fu, Hongbing ^{[3
,5
,6
,7
]}

Zhang, Qichun ^{[1
,4
]}

机构：

[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore

[2] Beijing Normal Univ, Coll Chem, Beijing 100875, Peoples R China

[3] Chinese Acad Sci, Inst Chem, BNLMS, Beijing 100190, Peoples R China

[4] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 639798, Singapore

[5] Capital Normal Univ, Beijing Key Lab Opt Mat & Photon Devices, Dept Chem, Beijing 100048, Peoples R China

[6] Tianjin Univ, Dept Chem, Tianjin Key Lab Mol Optoelect Sci, Tianjin 300072, Peoples R China

[7] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 55期

关键词：

FULL CHARACTERIZATION; HIGHER ACENES; AZAACENES; BEHAVIOR;

D O I：

10.1039/c7cc03898d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Here, we present our recent progress on the synthesis, crystal structure, physical properties and DFT calculations of a novel large pyrene-fused N-heteroacene (15RINGS) with 15 aromatic six-membered rings linearly fused in one row. The long conjugated backbone (more than 35 angstrom) of 15RINGS possesses a dual-bending feature (the bending angle is about 13.2 degrees).

引用

页码：7772 / 7775

页数：4

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