The effect of the unpaired d-orbital electron number in Fe and Co catalysts on Fischer-Tropsch synthesis

被引：10
作者：
Zhai, Yongbiao [1 ,2 ]
Zhang, Juan [1 ]
Sun, Jiaqiang [1 ]
Xue, Yingying [1 ,2 ]
Chen, Zheng [1 ,2 ]
Chen, Min [1 ,3 ]
Wang, Buhuan [1 ,2 ]
Chen, Jiangang [1 ]
机构：
[1] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Shanghai Univ, Coll Environm Engn, Shanghai 200444, Peoples R China
来源：
CATALYSIS SCIENCE & TECHNOLOGY | 2016年 / 6卷 / 22期
基金：
中国国家自然科学基金;
关键词：
DIATOMIC-MOLECULES; IRON CATALYSTS; ADSORPTION; SURFACES; DESIGN; OXIDE;
D O I：
10.1039/c6cy01803c
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The unpaired d electron number is a significant parameter in designing highly active and selective catalysts. In this communication, we take Fe- and Co-based catalysts as examples. The unpaired d electron number was calculated, and the results show that it can be used as an indicator to select electron promoters for different catalysts.
引用
收藏
页码：7942 / 7945
页数：4
相关论文
共 50 条
  • [41] Effect of CO2-Rich Syngas on the Chemical State of Fe(110) during Fischer-Tropsch Synthesis
    Degerman, David
    Shipilin, Mikhail
    Lomker, Patrick
    Soldemo, Markus
    Goodwin, Christopher M.
    Wagstaffe, Michael
    Borner, Mia
    Schlueter, Christoph
    Amann, Peter
    Nilsson, Anders
    JOURNAL OF PHYSICAL CHEMISTRY C, 2024, 128 (13) : 5542 - 5552
  • [42] Impact of the support material on the phosphorus poisoning on Co-based catalysts for Fischer-Tropsch synthesis
    Ivanez, Oscar
    Rovira, Albert Miro i
    Blekkan, Edd A.
    CATALYSIS TODAY, 2024, 441
  • [43] Detailed kinetics of the Fischer-Tropsch synthesis over Co-based catalysts containing sulphur
    Visconti, Carlo Giorgio
    Lietti, Luca
    Tronconi, Enrico
    Forzatti, Pio
    Zennaro, Roberto
    Rossini, Stefano
    CATALYSIS TODAY, 2010, 154 (3-4) : 202 - 209
  • [44] Removal of sodium compounds from Co/SBA-15 catalysts for Fischer-Tropsch Synthesis
    da Silva, Lidiane Sabino
    Cher, Gabriela Gonzaga
    Scaramelo Baldanza, Maria Auxiliadora
    dos Santos Teixeira da Silva, Victor Luis
    Arroyo, Pedro Augusto
    ACTA SCIENTIARUM-TECHNOLOGY, 2020, 42
  • [45] LOW-TEMPERATURE FISCHER-TROPSCH SYNTHESIS USING PLASMA-SYNTHESIZED NANOMETRIC CO/C AND FE/C CATALYSTS
    Aluha, James
    Braidy, Nadi
    Dalai, Ajay
    Abatzoglou, Nicolas
    CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 2016, 94 (08) : 1504 - 1515
  • [46] Insights into the effect of Fe-Zn interaction on tunable reactivity in Fischer-Tropsch synthesis
    Wei, Chongyang
    Han, Xiaoxue
    Huang, Shouying
    Liang, Haoting
    Wang, Yidan
    Li, Ting
    Wang, Yong
    Wang, Yue
    Ma, Xinbin
    CHEMICAL ENGINEERING SCIENCE, 2025, 301
  • [47] Microcalorimetric studies of H2 and CO on Co/γ-Al2O3 catalysts for Fischer-Tropsch synthesis
    Patanou, Eleni
    Tveten, Erik Z.
    Chen, De
    Holmen, Anders
    Blekkan, Edd A.
    CATALYSIS TODAY, 2013, 214 : 19 - 24
  • [48] δ-Alumina supported cobalt catalysts promoted by ruthenium for Fischer-Tropsch synthesis
    Kungurova, Olga A.
    Khassin, Alexander A.
    Cherepanova, Svetlana V.
    Saraev, Andrey A.
    Kaichev, Vasily V.
    Shtertser, Natalya V.
    Chermashentseva, Galina K.
    Gerasimov, Evgeny Yu.
    Paukshtis, Evgeny A.
    Vodyankina, Olga V.
    Minyukova, Tatyana P.
    Abou-Jaoude, Georges
    APPLIED CATALYSIS A-GENERAL, 2017, 539 : 48 - 58
  • [49] Carbon-Silica Composite as an Effective Support for Iron Fischer-Tropsch Synthesis Catalysts
    Chernayskii, Petr A.
    Kazantsev, Ruslan, V
    Pankina, Galina, V
    Maslakov, Konstantin, I
    Lupin, Boris S.
    Eliseev, Oleg L.
    ENERGY TECHNOLOGY, 2019, 7 (04)
  • [50] Origin of the Formation of Nanoislands on Cobalt Catalysts during Fischer-Tropsch Synthesis
    Banerjee, Arghya
    van Bave, Alexander P.
    Kuipers, Herman P. C. E.
    Saeys, Mark
    ACS CATALYSIS, 2015, 5 (08): : 4756 - 4760
12345