The effect of the unpaired d-orbital electron number in Fe and Co catalysts on Fischer-Tropsch synthesis

被引：10
|
作者：
Zhai, Yongbiao [1 ,2 ]
Zhang, Juan [1 ]
Sun, Jiaqiang [1 ]
Xue, Yingying [1 ,2 ]
Chen, Zheng [1 ,2 ]
Chen, Min [1 ,3 ]
Wang, Buhuan [1 ,2 ]
Chen, Jiangang [1 ]
机构：
[1] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Shanghai Univ, Coll Environm Engn, Shanghai 200444, Peoples R China
来源：
CATALYSIS SCIENCE & TECHNOLOGY | 2016年 / 6卷 / 22期
基金：
中国国家自然科学基金;
关键词：
DIATOMIC-MOLECULES; IRON CATALYSTS; ADSORPTION; SURFACES; DESIGN; OXIDE;
D O I：
10.1039/c6cy01803c
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The unpaired d electron number is a significant parameter in designing highly active and selective catalysts. In this communication, we take Fe- and Co-based catalysts as examples. The unpaired d electron number was calculated, and the results show that it can be used as an indicator to select electron promoters for different catalysts.
引用
收藏
页码：7942 / 7945
页数：4
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