Phospholyl compounds of nickel and uranium

被引：20

作者：

Arliguie, T ^{[1
]}

Ephritikhine, M ^{[1
]}

Lance, M ^{[1
]}

Nierlich, M ^{[1
]}

机构：

[1] CEA SACLAY,CNRS URA 331,DRECAM,DSM,SERV CHIM MOL,F-91191 GIF SUR YVETTE,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 524卷 / 1-2期

关键词：

phospholyl; nickel; uranium;

D O I：

10.1016/S0022-328X(96)06447-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The phospholyl nickel compound [{Ni(eta(5)-C(4)Me(4)P)(mu-eta(1)-C(4)Me(4)P)}(2)] 1 was prepared by treating NiCl2 with two equivalents of KC(4)Me(4)P in pyridine, whereas reaction of NiCl2 with two equivalents of [U(eta(5)-C(4)Me(4)P)(3)Cl] or an excess of [U(eta(5)-C(4)Me(4)P)(2)Cl-2] afforded the trinuclear complex [Ni{(mu-eta(5),eta(1)-C(4)Me(4)P)(2)UCl2}(2)] 2. Reduction of a 1:2 mixture of 1 and [U(eta(5)-C(4)Me(4)P)(2)Cl-2] by sodium amalgam in tetrahydrofuran gave the tetranuclear compound [{Ni-2(mu-eta(1)-C(4)Me(4)P)(2)}{(mu-eta(5),eta(1)-C(4)Me(4)P)(2)UCl2}(2) . 3C(4)H(8)O] 3. The crystal structures of 1, 2 and 3 have been determined.

引用

页码：293 / 297

页数：5

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