New Ruthenium Complexes Based on Tetradentate Bipyridine Ligands for Catalytic Hydrogenation of Esters

被引：11
作者：
Wang, Fangyuan [1 ,2 ]
Tan, Xuefeng [1 ,2 ]
Lv, Hui [1 ,2 ,3 ]
Zhang, Xumu [1 ,2 ,4 ]
机构：
[1] Wuhan Univ, Minist Educ, Key Lab Biomed Polymers, Wuhan 430072, Hubei, Peoples R China
[2] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China
[3] Chinese Acad Sci, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China
[4] South Univ Sci & Technol China, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2016年 / 11卷 / 15期
基金：
中国国家自然科学基金;
关键词：
alcohols; esters; pyridine ligands; ruthenium; synthetic methods; SELECTIVE HYDROGENATION; BIFUNCTIONAL ADDITION; EFFICIENT CATALYSTS; CARBOXYLIC ESTERS; CHIRAL ALCOHOLS; REDUCTION;
D O I：
10.1002/asia.201600506
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
New bipyridinemethanamine-containing tetradentate ligands and their corresponding ruthenium complexes have been synthesized. The synthesized complexes performed well in the hydrogenation of a variety of esters with high efficiency (TON up to 9700) giving alcohols in good yields.
引用
收藏
页码：2103 / 2106
页数：4
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