A comparative study of the activity and stability of SO42-/MxOy (M = Zr, Sn, Ti) for dehydration of sorbitol and glucose

被引：8
作者：
Deng, Qingbo [1 ]
Zhang, Yi [1 ,2 ]
Huang, Zilong [1 ]
Lin, Ziyan [1 ]
Chen, Tong [2 ]
机构：
[1] Hubei Univ Arts & Sci, Coll Chem Engn, Xiangyang 441053, Peoples R China
[2] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China
来源：
RESEARCH ON CHEMICAL INTERMEDIATES | 2022年 / 48卷 / 11期
关键词：
Solid acid; Dehydration; Sulfated metal oxide; Sorbitol; Glucose; BRONSTED ACIDIC SITES; SULFATED ZIRCONIA; CATALYZED DEHYDRATION; ISOSORBIDE PRODUCTION; CONVERSION; TRANSFORMATIONS; SO42-/ZRO2; PHOSPHATE; CELLULOSE; FRUCTOSE;
D O I：
10.1007/s11164-022-04820-8
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three kinds of typical solid superacid catalysts SO42-/SnO2, SO42-/TiO2 and SO42-/ZrO2 were prepared by impregnation-calcination method, and subsequently used for the dehydration of bio-based sorbitol and glucose to make a systematic comparative study of their catalytic activity and reusability. It was found that the ratio of Bronsted to Lewis acid sites of sulfated metal oxides depended much on the coverage degree of surface sulfate species, which further significantly affected the dehydration efficiency. SO42-/SnO2 and SO42-/TiO2 with higher Bronsted acid ratio possessed higher catalytic activity in sorbitol dehydration, however displayed worse in glucose dehydration due to the lack of Lewis acid sites. Furthermore, SO42-/ZrO2 possessed stronger bonding ability between sulfur species and metal oxide surface, thus showed obviously better stability and reusability compared with SO42-/TiO2 and SO42-/SnO2.
引用
收藏
页码：4693 / 4709
页数：17
相关论文
共 56 条
  • [1] ACIDIC PROPERTIES OF SULFATED ZIRCONIA - AN INFRARED SPECTROSCOPIC STUDY
    BABOU, F
    COUDURIER, G
    VEDRINE, JC
    [J]. JOURNAL OF CATALYSIS, 1995, 152 (02) : 341 - 349
  • [2] Technology development for the production of biobased products from biorefinery carbohydrates-the US Department of Energy's "Top 10" revisited
    Bozell, Joseph J.
    Petersen, Gene R.
    [J]. GREEN CHEMISTRY, 2010, 12 (04) : 539 - 554
  • [3] Isosorbide production from sorbitol over porous zirconium phosphate
    Cao, Dong
    Yu, Bo
    Zhang, Shaoyin
    Cui, Li
    Zhang, Jianghua
    Cai, Weijie
    [J]. APPLIED CATALYSIS A-GENERAL, 2016, 528 : 59 - 66
  • [4] Transformations of biomass-derived platform molecules: from high added-value chemicals to fuels via aqueous-phase processing
    Carlos Serrano-Ruiz, Juan
    Luque, Rafael
    Sepulveda-Escribano, Antonio
    [J]. CHEMICAL SOCIETY REVIEWS, 2011, 40 (11) : 5266 - 5281
  • [5] Direct conversion of glucose to 5-hydroxymethylfurfural using a mixture of niobic acid and niobium phosphate as a solid acid catalyst
    Catrinck, Mariana N.
    Ribeiro, Emerson S.
    Monteiro, Robson S.
    Ribas, Rogerio M.
    Barbosa, Marcio H. P.
    Teofilo, Reinaldo F.
    [J]. FUEL, 2017, 210 : 67 - 74
  • [6] SUPERACID AND CATALYTIC PROPERTIES OF SULFATED ZIRCONIA
    CHEN, FR
    COUDURIER, G
    JOLY, JF
    VEDRINE, JC
    [J]. JOURNAL OF CATALYSIS, 1993, 143 (02) : 616 - 626
  • [7] Chemical routes for the transformation of biomass into chemicals
    Corma, Avelino
    Iborra, Sara
    Velty, Alexandra
    [J]. CHEMICAL REVIEWS, 2007, 107 (06) : 2411 - 2502
  • [8] Dosen-Micovic L, 1998, J PHYS ORG CHEM, V11, P887, DOI 10.1002/(SICI)1099-1395(199812)11:12<887::AID-POC78>3.0.CO
  • [9] 2-9
  • [10] Synthesis of isosorbide: an overview of challenging reactions
    Dussenne, C.
    Delaunay, T.
    Wiatz, V.
    Wyart, H.
    Suisse, I.
    Sauthier, M.
    [J]. GREEN CHEMISTRY, 2017, 19 (22) : 5332 - 5344
123456