Densities and Viscosities for the Ternary System of 1,2,3,4-Tetrahydronaphthalene plus Isopropylcyclohexane plus Cyclopropanemethanol and Corresponding Binaries at T = (293.15 to 343.15) K

被引:8
|
作者
Liu, Zhaoshan [1 ]
Cai, Mengsha [1 ]
Xu, Sanshu [2 ]
Guo, Yongsheng [1 ]
Fang, Wenjun [1 ]
机构
[1] Zhejiang Univ, Dept Chem, Hangzhou 310058, Zhejiang, Peoples R China
[2] AVIC, Nanjing Engn Inst Aircraft Syst, Nanjing 210000, Jiangsu, Peoples R China
来源
基金
中国国家自然科学基金;
关键词
REFRACTIVE-INDEXES; EXCESS VOLUMES; SOUND VELOCITIES; SURFACE-TENSION; BULK MODULUS; N-HEXADECANE; FLASH-POINT; MIXTURES; ETHANOL; LIQUIDS;
D O I
10.1021/acs.jced.8b00662
中图分类号
O414.1 [热力学];
学科分类号
摘要
Measurements on density and viscosity at atmospheric pressure for the ternary system 1,2,3,4-tetrahydronaphthalene (1) + isopropylcyclohexane (2) + cyclopropanemethanol (3) and three corresponding binary systems from (293.15 to 343.15) K have been carried out over the whole composition range. The excess molar volumes (V-m(E)) and viscosity deviations (Delta eta) of the ternary system have been derived from the experimental data and then fitted to the Cibulka, Singh, Redlich-Kister, and Nagata-Tamura equations, respectively. The binary subsystems were correlated by Redlich-Kister equation. For the system of 1,2,3,4-tetrahydronaphthalene + isopropylcyclohexane, the curve of the V-m(E) reveals a wing shape. The V-m(E) values are positive for the other two binary systems of 1,2,3,4-tetrahydronaphthalene + cyclopropanemethanol and isopropylcyclohexane + cyclopropanemethanol. While the value of Delta eta for all three binary systems is negative over the entire composition range. The results are interpreted with molecular interactions and structural effects.
引用
收藏
页码:4596 / 4605
页数:10
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