Effect of dispersion on the relaxation-retardation time scale ratio

被引：21

作者：

Ito, N ^{[1
]}

Richert, R ^{[1
]}

机构：

[1] Arizona State Univ, Dept Chem & Biochem, Tempe, AZ 85287 USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 2005年 / 123卷 / 10期

关键词：

D O I：

10.1063/1.2036972

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effect of dispersion on the relaxation-retardation time scale ratio was studied. The Cole-Davidson (CD)-type dielectric function was treated numerically. The longitudinal time is a typical benchmark for estimating the time scale of fast solvation responses on the basis of dielectric relaxation data. Relaxation-time dispersions are capable of shifting the relaxation or modulus time scales much more towards fast responses relative to the Debye case.

引用

页数：2

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