Iron-catalyzed asymmetric hydrosilylation of ketones

被引：72

作者：

Zuo, Ziqing ^{[1
]}

Zhang, Lei ^{[1
]}

Leng, Xuebing ^{[1
]}

Huang, Zheng ^{[1
]}

机构：

[1] Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 24期

基金：

中国国家自然科学基金;

关键词：

ENANTIOSELECTIVE HYDROSILYLATION; CARBONYL-COMPOUNDS; ALKENE HYDROBORATION; CHIRAL LIGANDS; COMPLEXES; ARYL; HYDROGENATION; REDUCTION; EFFICIENT; POLYMETHYLHYDROSILOXANE;

D O I：

10.1039/c5cc00612k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of iron complexes of chiral iminopyridine-oxazoline (IPO) ligands have been synthesized. The most sterically hindered iron catalyst exhibits excellent activity (up to 99% yield) and high enantioselectivity (up to 93% ee) in asymmetric hydrosilylation of aryl ketones.

引用

页码：5073 / 5076

页数：4

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