Refining effect of trace addition of B and the impurity elements in Al-Si-Cu-Mn-Ni heat-resistant alloy on primary Mn-rich phase

被引:3
作者
Li, Guangjing [1 ]
Liao, Hengcheng [1 ]
Teng, Huaijin [1 ]
Yang, Linlong [2 ]
Guo, Huiting [2 ]
机构
[1] Southeast Univ, Jiangsu Key Lab Adv Metall Mat, Sch Mat Sci & Engn, Nanjing 211189, Peoples R China
[2] Suzhou Mingzhi Technol Co Ltd, Suzhou 215216, Peoples R China
关键词
Cast; Crystal structure; Microstructure; Heat-resistant aluminum alloy; E2EM model; Refining effect; GRAIN-REFINEMENT;
D O I
10.1016/j.matlet.2021.131563
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Refining effect of trace B addition in Al-Si-Cu-Mn-Ni alloy on primary Mn-rich phase was studied by OM, SEM, TEM and HRTEM. Addition of trace B (0.02 wt%) remarkably alters the morphology of primary Mn-rich phase from coarse dendritic to fine short-rod-like or blocky, and significantly reduces its size. TEM/HRTEM characterizations clarify that the fine particles embedded in the short-rod-like or blocky Al3MnSi2 phase are (V,Ti,Mn) B2 phase. One good matching orientation relationship between Al3MnSi2 phase and (V,Ti,Mn)B2 phase is confirmed by E2EM model calculation, indicating that (V,Ti,Mn)B2 phase has a strong potential as the heterogeneous nucleation substrate for Al3MnSi2 phase during solidification. So, trace addition of B and the impurity elements in Al-Si-Cu-Mn-Ni alloy leads to the formation of fine (V,Ti,Mn)B2 particles that greatly enhances the nucleation of primary Al3MnSi2 phase and thus significantly reduces its size.
引用
收藏
页数:4
相关论文
共 16 条
  • [1] Design of an in-situ multi-scale particles reinforced (Al2O3+ZrB2+AlN)/Al composite with high strength, elasticity modulus and thermal stability
    Bian, Yihan
    Gao, Tong
    Liu, Guiliang
    Ma, Xia
    Ren, Yingying
    Liu, Xiangfa
    [J]. MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2020, 775
  • [2] Grain refinement and tensile properties improvement of aluminum foundry alloys by inoculation with Al-B master alloy
    Chen, Zongning
    Wang, Tongmin
    Gao, Lei
    Fu, Hongwang
    Li, Tingju
    [J]. MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2012, 553 : 32 - 36
  • [3] High-temperature mechanical properties and fracture mechanisms of Al-Si piston alloy reinforced with in situ TiB2 particles
    Han, Gang
    Zhang, Weizheng
    Zhang, Guohua
    Peng, Zengjian
    Wang, Yanjun
    [J]. MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2015, 633 : 161 - 168
  • [4] Thermodynamic and Kinetic Analyses of the Removal of Impurity Titanium and Vanadium from Molten Aluminum for Electrical Conductor Applications
    Khaliq, Abdul
    Alghamdi, A. S.
    Rajhi, Wajdi
    Subhani, Tayyab
    Ramadan, Mohamed
    Halim, K. S. Abdel
    Qian, Ma
    [J]. METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE, 2021, 52 (05): : 3130 - 3141
  • [5] Removal of Vanadium from Molten Aluminum-Part I. Analysis of VB2 Formation
    Khaliq, Abdul
    Rhamdhani, Muhammad Akbar
    Brooks, Geoffrey A.
    Grandfield, John F.
    [J]. METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE, 2014, 45 (02): : 752 - 768
  • [6] A crystallographic identification of intermetallic phases in Al-Si alloys
    Kral, MV
    [J]. MATERIALS LETTERS, 2005, 59 (18) : 2271 - 2276
  • [7] On the constitution of the system Al-Mn-Si
    Krendelsberger, N
    Weitzer, F
    Schuster, JC
    [J]. METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2002, 33 (11): : 3311 - 3319
  • [8] Two quite different primary Mn-rich phases in Al-Si-Cu-Mn heat-resistant alloy and its effect to mechanical properties
    Li, Guangjing
    Liao, Hengcheng
    Xu, Aiqun
    [J]. MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2018, 730 : 36 - 40
  • [9] Peritectic reaction between two primary Mn-rich phases during solidification of Al-Si-Cu-Mn heat-resistant alloy and the effect of cooling rate on it
    Li, Guangjing
    Liao, Hengcheng
    Xu, Aiqun
    Tang, Jingfan
    Zhao, Baojun
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2018, 753 : 239 - 246
  • [10] Ni-Rich Phases in Al-12%Si-4%Cu-1.2%Mn-x%Ni Heat-Resistant Alloys and Effect of Ni-Alloying on Tensile Mechanical Properties
    Liao, Hengcheng
    Li, Guangjin
    Liu, Qu
    [J]. JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE, 2019, 28 (09) : 5398 - 5408