pH-controlled the formation of 4-sulfocalix[4]arene-based 1D and 2D coordination polymers

被引：24
作者：
Lin, Rong-Guang [1 ]
Long, La-Sheng [1 ]
Huang, Rong-Bin [1 ]
Zheng, Lan-Sun [1 ]
机构：
[1] Xiamen Univ, Coll Chem & Chem Engn, Dept Chem, State Key Lab Phys Chem Solid Surface, Xiamen 361005, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2007年 / 10卷 / 11期
基金：
中国国家自然科学基金;
关键词：
4-Sulfocalix[4]arene; manganese; coordination polymer; pH-dependent;
D O I：
10.1016/j.inoche.2007.08.003
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three manganese/4-sulfocalix[4]arene complexes, namely, {H[(C28H20O16S4)Mn(H2O)(4)Mn-0.5(H2O)(2)]}(n) center dot 6nH(2)O (1), {NH4[(C28H20O16S4)Mn(H2O)(4)Mn-0.5(H2O)(2)]}(n) center dot 5nH(2)O (2), [(C28H20O16S4)Mn-2(H2O)(8)](n) center dot 6nH(2)O (3), have been synthesized under different pH conditions. Complex 1, which exhibits a one-dimensional (1D) structure, is formed at [H+] = 2.0 mol L-1. Reaction at pH 4 leads to another one-dimensional (1D) coordination polymer of 2. At pH 5, a two-dimensional (2D) coordination polymer of complex 3 is formed, showing clearly structural effects on pH response. (c) 2007 Elsevier B.V. All rights reserved.
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收藏
页码：1257 / 1261
页数：5
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