Reactions of d0 alkylidene and amide complexes with silanes

被引：10
|
作者：
Diminnie, JB
Liu, XZ
Cai, H
Wu, ZZ
Blanton, JR
Chen, TN
Tuinman, AA
Quisenberry, KT
Vallet, CE
Zuhr, RA
Beach, DB [1 ]
Peng, ZH
Wu, YD
Concolino, TE
Rheingold, AL
Xue, ZL
机构：
[1] Oak Ridge Natl Lab, Div Chem & Analyt Sci, Oak Ridge, TN 37831 USA
[2] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA
[3] Oak Ridge Natl Lab, Surface Modificat & Characterizat Res Ctr, Oak Ridge, TN 37831 USA
[4] Hong Kong Univ Sci & Technol, Dept Chem, Hong Kong, Hong Kong, Peoples R China
[5] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA
来源：
PURE AND APPLIED CHEMISTRY | 2001年 / 73卷 / 02期
关键词：
D O I：
10.1351/pac200173020331
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reactions of silanes with d(o) Ta alkylidene and Group 4 amide complexes were found to involve the initial attack on silicon atoms in the silanes by nucleophilic alkylidene carbon or amide nitrogen atoms. The reaction of (Me3SiCH2)(3)Ta(PMe3)[=CHSiMe3] (1) with H2SiR'Ph (R' = Me, Ph) gave (Me3SiCH2)(3)Ta[=C(SiMe3)SiHR'Ph] (2a-b). Similar reactions of these two silanes and (H2PhSi)(2)CH2 with (Me3SiCH2)Ta(PMe3)(2)[=CHR](2) (R = SiMe3, 3; CMe3, 4) yielded novel metallasilacyclobutadienes and a metalladisilacyclohexadiene, respectively. In comparison, the reactions between M(NMe2)(4) (M = Ti, Zr, Hf) and silanes were found to give aminosilanes and metal amide hydride species which were perhaps involved in the formation of titanium-silicon-nitride (Ti-Si-N) ternary materials.
引用
收藏
页码：331 / 335
页数：5
相关论文
共 50 条
  • [21] Search for the decay D0 → γγ and measurement of the branching fraction for D0 → π0π0
    Lees, J. P.
    Poireau, V.
    Prencipe, E.
    Tisserand, V.
    Garra Tico, J.
    Grauges, E.
    Martinelli, M.
    Milanes, D. A.
    Palano, A.
    Pappagallo, M.
    Eigen, G.
    Stugu, B.
    Sun, L.
    Brown, D. N.
    Kerth, L. T.
    Kolomensky, Yu. G.
    Lynch, G.
    Koch, H.
    Schroeder, T.
    Asgeirsson, D. J.
    Hearty, C.
    Mattison, T. S.
    McKenna, J. A.
    Khan, A.
    Blinov, V. E.
    Buzykaev, A. R.
    Druzhinin, V. P.
    Golubev, V. B.
    Kravchenko, E. A.
    Onuchin, A. P.
    Serednyakov, S. I.
    Skovpen, Yu. I.
    Solodov, E. P.
    Todyshev, K. Yu.
    Yushkov, A. N.
    Bondioli, M.
    Curry, S.
    Kirkby, D.
    Lankford, A. J.
    Mandelkern, M.
    Stoker, D. P.
    Atmacan, H.
    Gary, J. W.
    Liu, F.
    Long, O.
    Vitug, G. M.
    Campagnari, C.
    Hong, T. M.
    Kovalskyi, D.
    Richman, J. D.
    PHYSICAL REVIEW D, 2012, 85 (09):
  • [22] RECENT ADVANCES IN THE CHEMISTRY OF D(0) ALKYLIDENE AND METALLACYCLOBUTANE COMPLEXES
    FELDMAN, J
    SCHROCK, RR
    PROGRESS IN INORGANIC CHEMISTRY, 1991, 39 : 1 - 74
  • [23] Reactions of alkyl alkylidene complexes with silanes. Synthesis and characterization of novel tantalum 1,1-metallasilacyclobutadiene and disilyl-substituted alkylidene complexes
    J Am Chem Soc, 51 (12657):
  • [24] Reactions of alkyl alkylidene complexes with silanes. Synthesis and characterization of novel tantalum 1,1-metallasilacyclobutadiene and disilyl-substituted alkylidene complexes
    Diminnie, JB
    Xue, ZL
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (51) : 12657 - 12658
  • [25] RADICAL COMPLEXES OF D0 AND D10 METAL IONS
    CLOPATH, P
    ZELEWSKY, AV
    CHIMIA, 1971, 25 (07) : 241 - &
  • [26] Branching fractions for D0→K+K- and D0→π+π-, and a search for CP violation in D0 decays
    Aitala, EM
    Amato, S
    Anjos, JC
    Appel, JA
    Ashery, D
    Banerjee, S
    Bediaga, I
    Blaylock, G
    Bracker, SB
    Burchat, PR
    Burnstein, RA
    Carter, T
    Carvalho, HS
    Copty, NJ
    Cremaldi, LM
    Darling, C
    Denisenko, K
    Fernandez, A
    Fox, G
    Gagnon, P
    Gobel, C
    Gounder, K
    Halling, AM
    Herrera, G
    Hurvits, G
    James, C
    Kasper, PA
    Kwan, S
    Langs, DC
    Leslie, J
    Lundberg, B
    MayTal-Beck, S
    Meadows, B
    Neto, JRTD
    Milburn, RH
    de Miranda, JM
    Napier, A
    Nguyen, A
    d'Oliveira, AB
    O'Shaughnessy, K
    Peng, KC
    Perera, LP
    Purohit, MV
    Quinn, B
    Radeztsky, S
    Rafatian, A
    Reay, NW
    Reidy, JJ
    dos Reis, AC
    Rubin, HA
    PHYSICS LETTERS B, 1998, 421 (1-4) : 405 - 411
  • [27] D介子衰变Γ（D0→K+K-）/Γ（D0→π+π-）
    马中骐
    东方晓
    岳宗五
    周咸建
    薛丕友
    高能物理与核物理, 1981, (01) : 130 - 133
  • [28] Measurement of the ratio B(D0→π+π-π0)/B(D0→K-π+π0) and the time-integrated CP asymmetry in D0→π+π-π0
    Arinstein, K.
    Adachi, I.
    Aihara, H.
    Aulchenko, V.
    Aushev, T.
    Aziz, T.
    Bahinipati, S.
    Bakich, A. M.
    Balagura, V.
    Barberio, E.
    Bay, A.
    Bedny, I.
    Belous, K.
    Bhardwaj, V.
    Bitenc, U.
    Blyth, S.
    Bondar, A.
    Bozek, A.
    Bracko, M.
    Browder, T. E.
    Chao, Y.
    Chen, A.
    Chen, W. T.
    Cheon, B. G.
    Chistov, R.
    Cho, I. -S.
    Choi, Y.
    Cole, S.
    Dalseno, J.
    Danilov, M.
    Dash, M.
    Drutskoy, A.
    Eidelman, S.
    Epifanov, D.
    Gabyshev, N.
    Goldenzweig, P.
    Golob, B.
    Ha, H.
    Haba, J.
    Hara, K.
    Hayasaka, K.
    Hayashii, H.
    Hazumi, M.
    Hoshi, Y.
    Hou, W. -S.
    Iijima, T.
    Inami, K.
    Ishikawa, A.
    Ishino, H.
    Itoh, R.
    PHYSICS LETTERS B, 2008, 662 (02) : 102 - 110
  • [29] Reactions of tantalum alkylidene complexes with silanes. Synthesis and characterization of novel metallasilacyclodiene complexes and kinetic and mechanistic studies of their formation
    Diminnie, JB
    Blanton, JR
    Cai, H
    Quisenberry, KT
    Xue, ZL
    ORGANOMETALLICS, 2001, 20 (08) : 1504 - 1514
  • [30] A possible arena for searching new physics -: the Γ(D0→ρ0γ)/Γ(D0→ωγ) ratio
    Fajfer, S
    Prelovsek, S
    Singer, P
    Wyler, D
    PHYSICS LETTERS B, 2000, 487 (1-2) : 81 - 86
12345