Cyclodextrins and their applications in aqueous-phase metal-catalyzed reactions

被引：94
作者：
Hapiot, Frederic [1 ,2 ,3 ]
Ponchel, Anne [1 ,2 ,3 ]
Tilloy, Sebastien [1 ,2 ,3 ]
Monflier, Eric [1 ,2 ,3 ]
机构：
[1] Univ Lille Nord France, F-59000 Lille, France
[2] CNRS, UMR 8181, Unite Catalyse & Chim Solide, F-75700 Paris, France
[3] Fac Sci Jean Perrin, UArtois, F-62307 Lens, France
来源：
COMPTES RENDUS CHIMIE | 2011年 / 14卷 / 2-3期
关键词：
Cyclodextrin; Aqueous organometallic catalysis; Nanoparticles; Supported metals; Metal powder; MODIFIED BETA-CYCLODEXTRINS; CAPPED PALLADIUM NANOPARTICLES; MASS-TRANSFER PROMOTER; HOST-GUEST CHEMISTRY; HIGHER ALPHA-OLEFINS; METHYLATED CYCLODEXTRINS; ORGANOMETALLIC CATALYSIS; BIPHASIC HYDROFORMYLATION; MOLECULAR RECOGNITION; WACKER-OXIDATION;
D O I：
10.1016/j.crci.2010.04.003
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
During these last years, cyclodextrins have greatly contributed to the development of catalytic processes in water. These cyclic oligosaccharides composed of 6(alpha), 7(beta) or 8(gamma) glucopyranose units improve the mass transfer in aqueous-organic two-phase systems and are useful compounds to design new catalysts. Thus, chemically modified cyclodextrins can be used to: (1) significantly increase the rate and selectivity of reactions catalyzed by water-soluble organometallic complexes; (2) design new water-soluble ligands for aqueous organometallic catalysis; (3) stabilize catalytically active noble metal nanoparticles in water; (4) facilitate reactions catalyzed by supported metals or metallic powder in water. (C) 2010 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.
引用
收藏
页码：149 / 166
页数：18
相关论文
共 134 条
[21]  
Caron L, 2003, EUR J INORG CHEM, P595
[22]   One and two-dimensional NMR investigations of the inclusion of the monosulfonated triphenylphosphine in the β-cyclodextrin [J].
Caron, L ;
Christine, C ;
Tilloy, S ;
Monflier, E ;
Landy, D ;
Fourmentin, S ;
Surpateanu, G .
SUPRAMOLECULAR CHEMISTRY, 2002, 14 (01) :11-20
[23]  
CARON L, 2000, J INCLUSION PHENOM, V38, P661
[24]   Eco-efficient catalytic hydrodechlorination of carbon tetrachloride in aqueous cyclodextrin solutions [J].
Cassez, A ;
Ponchel, A ;
Bricout, H ;
Fourmentin, S ;
Landy, D ;
Monflier, E .
CATALYSIS LETTERS, 2006, 108 (3-4) :209-214
[25]   Chemically modified cyclodextrins adsorbed on Pd/C particles: New opportunities to generate highly chemo- and stereoselective catalysts for Heck reaction [J].
Cassez, Andy ;
Kania, Nicolas ;
Hapiot, Frederic ;
Fourmentin, Sophie ;
Monflier, Eric ;
Ponchel, Anne .
CATALYSIS COMMUNICATIONS, 2008, 9 (06) :1346-1351
[26]   Unexpected multifunctional effects of methylated cyclodextrins in a palladium charcoal-catalyzed Suzuki-Miyaura reaction [J].
Cassez, Andy ;
Ponchel, Anne ;
Hapiot, Frederic ;
Monflier, Eric .
ORGANIC LETTERS, 2006, 8 (21) :4823-4826
[27]  
COLEHAMILTON DJ, 2006, SERIES CATALYSIS MET
[28]   Industrial aqueous biphasic catalysis: Status and directions [J].
Cornils, B .
ORGANIC PROCESS RESEARCH & DEVELOPMENT, 1998, 2 (02) :121-127
[29]  
Cornils B., 2004, AQUEOUS PHASE ORGANO, V2nd
[30]   Scanning tunneling microscopy investigation of an inclusion complex between the β-cyclodextrin and the sodium salt of the trisulfonated triphenylphosphine [J].
Da Costa, A ;
Monflier, E ;
Landy, D ;
Fourmentin, S ;
Surpateanu, G .
SURFACE SCIENCE, 2001, 470 (03) :275-283
12345678910