Low-temperature oxy-nitriding of 316 L austenitic stainless steel for improved corrosion resistance in liquid lead-bismuth eutectic

被引：18

作者：

Chen, Guang ^{[1
]}

Wang, Jun ^{[1
]}

Zhang, Hongtao ^{[2
]}

Li, Longyi ^{[1
]}

Fan, Hongyuan ^{[1
]}

机构：

[1] Sichuan Univ, Sch Mech Engn, Chengdu 610065, Sichuan, Peoples R China

[2] Loughborough Univ, Dept Mat, Loughborough LE11 3TU, Leics, England

来源：

SCRIPTA MATERIALIA | 2021年 / 202卷

基金：

中国国家自然科学基金;

关键词：

316 L austenitic stainless steel; Low-temperature oxy-nitriding; Lead-bismuth eutectic; Dissolution corrosion; DISSOLUTION CORROSION; S-PHASE; OXIDATION; REACTOR; LBE; STABILITY; BEHAVIOR; CONTACT; 304L;

D O I：

10.1016/j.scriptamat.2021.114014

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The effects of low-temperature oxy-nitriding (LTON) treatment on the liquid lead-bismuth eutectic (LBE) corrosion behaviors of 316 L ASS were investigated in the stagnant liquid LBE under vacuum at 823 K. Results show that the untreated samples were severely selective leaching in contact with liquid LBE. LTON treatment produced an outer porous Fe-Cr spinel film and inner S phase layer on the sample surface, which transformed into a thicker spinel film containing gamma(low-N) and a region distributed with CrN precipitates after liquid LBE corrosion. This was mainly attributed to the oxidation and decomposition of S phase and inward diffusion of the interstitials, owing to S phase is a metastable phase and is easier to be oxidized than matrix at elevated temperatures. This inspired us that improving the ability to form protective oxide film for materials was maybe a good method to mitigate the liquid LBE corrosion. (C) 2021 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

引用

页数：6

共 32 条

[1] Overview of lead-cooled fast reactor activities [J].

Alemberti, Alessandro ;

Smirnov, Valery ;

Smith, Craig F. ;

Takahashi, Minoru .

PROGRESS IN NUCLEAR ENERGY, 2014, 77 :300-307

[2] The effects of cold working on the corrosion behavior of an austenitic stainless steel in liquid lead-bismuth eutectic under vacuum at 873 K [J].

Bian, Lu ;

Xia, Shuang ;

Bai, Qin ;

Li, Hui ;

Zhou, Bangxin .

JOURNAL OF NUCLEAR MATERIALS, 2018, 509 :591-599

[3] Role of Nitrogen Uptake During the Oxidation of 304L and 904L Austenitic Stainless Steels [J].

Cao, Yu ;

Norell, Mats .

OXIDATION OF METALS, 2013, 80 (5-6) :479-491

[4]

Chen G., CORROS SCI, V178

[5] Investigation of surface modifications for combating the molten aluminum corrosion of AISI H13 steel [J].

Chen, Guang ;

Xue, Ling ;

Wang, Jun ;

Tang, Zhenghua ;

Li, Xiaoying ;

Dong, Hanshan .

CORROSION SCIENCE, 2020, 174

[6] Combat molten aluminum corrosion of AISI H13 steel by low-temperature liquid nitrocarburizing [J].

Chen, Guang ;

Wang, Jun ;

Fan, Hongyuan ;

Wang, Danqi ;

Li, Xiaoying ;

Dong, Hanshan .

JOURNAL OF ALLOYS AND COMPOUNDS, 2019, 776 :702-711

[7]

Concetta F., 2015, Handbook on Lead-Bismuth Eutectic Alloy and Lead Properties, Materials Compatibility, Thermal-Hydraulics and Technologies: 2015 EditionIntroduction

[8] S-phase surface engineering of Fe-Cr, Co-Cr and Ni-Cr alloys [J].

Dong, H. .

INTERNATIONAL MATERIALS REVIEWS, 2010, 55 (02) :65-98

[9] Thermodynamic assessment of solubility and activity of iron, chromium, and nickel in lead bismuth eutectic [J].

Gosse, Stephane .

JOURNAL OF NUCLEAR MATERIALS, 2014, 449 (1-3) :122-131

[10] Twin boundary-accelerated ferritization of austenitic stainless steels in liquid lead-bismuth eutectic [J].

Hosemann, P. ;

Frazer, D. ;

Stergar, E. ;

Lambrinou, K. .

SCRIPTA MATERIALIA, 2016, 118 :37-40

← 1 2 3 4 →