Biphasic synthesis of hydrogen peroxide from carbon monoxide, water, and oxygen catalyzed by palladium complexes with bidentate nitrogen ligands

被引：0

作者：

Bianchi, D ^{[1
]}

Bortolo, R ^{[1
]}

D'Aloisio, R ^{[1
]}

Ricci, M ^{[1
]}

机构：

[1] EniChem SpA, Ctr Ric Novara, Ist G Donegani, I-28100 Novara, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1999年 / 38卷 / 05期

关键词：

hydrogen peroxide; N ligands; palladium;

D O I：

10.1002/(SICI)1521-3773(19990301)38:5<706::AID-ANIE706>3.0.CO;2-G

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Effective and stable Pd catalysts for the biphasic synthesis of hydrogen peroxide from carbon monoxide, oxygen, and water [Eq. (a)] can be obtained by the right choice of bidentate nitrogen ligand. The best turnover numbers (578) for this reaction have been achieved with palladium complexes with 2,9- dimethyl-4,7-diphenyl-1,10-phenanthroline ligands.

引用

页码：706 / 708

页数：3

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