Tetrahedral zinc in tetrakis(1-methyl-1H-imidazole-κN3)zinc bis(tetrafluoridoborate)

被引：3

作者：

Reedijk, Jan ^{[1
,2
]}

van Albada, Gerard A. ^{[1
]}

Limburg, Bart ^{[1
]}

Mutikainen, Ilpo ^{[3
]}

Turpeinen, Urho ^{[3
]}

机构：

[1] Leiden Univ, Leiden Inst Chem, NL-2300 RA Leiden, Netherlands

[2] King Saud Univ, Coll Sci, Dept Chem, Riyadh 11451, Saudi Arabia

[3] Univ Helsinki, Dept Chem, Inorgan Chem Lab, FIN-00014 Helsinki, Finland

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2012年 / 68卷

关键词：

Data-to-parameter ratio = 13.1; Mean σ(C-C) = 0.004 Å; R factor = 0.027; Single-crystal X-ray study; T = 173 K; wR factor = 0.068;

D O I：

10.1107/S1600536811054821

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Zn(C4H6N2)(4)](BF4)(2), the Zn-II ion is in a slightly distorted tetrahedral coordination geometry, with Zn-N distances in the range 1.980 (2)-1.991 (2) angstrom. The tetrahedral angles are in the range 104.93 (9)-118.81 (9)degrees.

引用

页码：M90 / +

页数：10

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