LaVO3: A true Kugel-Khomskii system

We show that the t22g perovskite LaVO3, in its orthorhombic phase, is a rare case of a system hosting an orbital-ordering Kugel???-Khomskii phase transition rather than being controlled by the Coulomb-enhanced crystal-field splitting. We find that, as a consequence of this, the magnetic transition is close to (and even above) the superexchange driven orbital-ordering transition, whereas typically magnetism arises at much lower temperatures than orbital ordering. Our results support the experimental scenario of orbital ordering and Gtype spin correlations just above the monoclinic-to-orthorhombic structural change. To explore the effects of crystal-field splitting and filling, we compare to YVO3 and t12g titanates. In all these materials the crystal field is sufficiently large to suppress the Kugel???-Khomskii phase transition.