The past, present, and future of the Yang reaction

被引：76
作者：
Chen, Chuo [1 ]
机构：
[1] Univ Texas Southwestern Med Ctr, Dept Biochem, 5323 Harry Hines Blvd, Dallas, TX 75390 USA
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2016年 / 14卷 / 37期
关键词：
C-H BONDS; PHOTOCHEMICALLY INDUCED ADDITION; PHOTOCATALYZED ADDITION; REMOTE OXIDATION; RADICAL-ADDITION; PHOTO-REDUCTION; ALPHA-ENONES; FUNCTIONALIZATION; ACTIVATION; PHOTOALKYLATION;
D O I：
10.1039/c6ob01214k
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Photoexcited ketones have diradical characteristics and are functionally similar to high-spin metal-oxo species that are frequently used to catalyze C-H oxidation. First discovered by Yang in 1958, photoexcited ketones can abstract a hydrogen atom from hydrocarbons inter-or intramolecularly. Coupling with atom-transfer, group-transfer, or radical addition, the Yang reaction can be used to achieve various types of C-H functionalization. We provide in this article an overview of triplet ketone-mediated or catalyzed C-H functionalization reactions.
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收藏
页码：8641 / 8647
页数：7
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