Catalytic Oxidation of Chlorobenzene over V2O5/TiO2-Carbon Nanotubes Composites

被引：55
作者：
Nie, Anmin [1 ]
Yang, Hangsheng [1 ]
Li, Qian [1 ]
Fan, Xiaoyu [1 ]
Qiu, Famin [1 ]
Zhang, Xiaobin [1 ]
机构：
[1] Zhejiang Univ, Dept Mat Sci & Engn, State Key Lab Silicon Mat, Hangzhou 310027, Zhejiang, Peoples R China
来源：
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2011年 / 50卷 / 17期
关键词：
MULTIWALLED CARBON NANOTUBES; OXIDE-BASED FORMULATIONS; CHLORINATED ORGANICS; O-DICHLOROBENZENE; FLUE-GASES; 1ST STEP; FT-IR; DIOXINS; DESTRUCTION; ADSORPTION;
D O I：
10.1021/ie200569a
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Catalysts V2O5/TiO2-carbon nanotubes (CNTs) were prepared by hydrothermal method and their activity for catalytic oxidation of chlorobenzene (CB) was studied. A CB conversion efficiency of 45% with a CO2 selectivity of 80% was achieved over V2O5 (1.2 wt 96)/TiO2-CNTs(8.6 wt 96) at a temperature as low as 200 C. It also has the highest removal efficiency of 95% at 300 degrees C. From the analysis of XRD, SEM, TEM, and TPR, the low-temperature activity of V2O5/TiO2-CNTs could be ascribed to the high S-BET, good dispersion of V2O5, and the possible adsorption of CB by free surface of CNTs.
引用
收藏
页码：9944 / 9948
页数：5
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