Synthesis of iron oxide embedded reduced graphene oxide composites with enhanced electrochemical performance as Li-ion battery anodes

被引:24
作者
Rosaiah, P. [1 ]
Zhu, Jinghui [1 ]
Zhang, Liwen [1 ]
Hussain, O. M. [2 ]
Qiu, Yejun [1 ]
机构
[1] Harbin Inst Technol, Dept Mat Sci & Engn, Shenzhen Engn Lab Flexible Transparent Conduct Fi, Shenzhen 518055, Peoples R China
[2] SV Univ, Dept Phys, Thin Film Lab, Tirupati 517502, Andhra Pradesh, India
关键词
Fe3O4; FeO; Reduced graphene oxide; Graphenothermal synthesis; Li-ion batteries; ELECTRODE PERFORMANCE; LITHIUM; FE3O4; CARBON; STORAGE; FILMS; SUPERCAPACITOR; NANOCOMPOSITES; FABRICATION; NANOFIBERS;
D O I
10.1016/j.jelechem.2018.12.048
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The iron oxide embedded reduced graphene oxide (rGO) composites were synthesized by a facile and cost-effective graphenothermal synthesis route. Initially, Fe3O4 was synthesized by thermal heating and used as a Fe source (in addition to GO) to prepare the Fe3O4/rGO composite. During reduction process, GO was reduced to rGO with three dimensional architecture and the micron/sub-micron Fe(3)O(4 )particles to nano-sized Fe3O4 particles. As a LIB anode, the Fe3O4/rGO composites displayed an initial discharge capacity of 1405 mAh g(-1) at 0.1 A g and maintained a capacity of 812 mAh g(-1) at 0.5 A g(-1) for 250 consecutive cycles. Furthermore, FeO/rGO electrodes exhibited better cycling stability for several cycles even at 0.5 A g(-1). So the composite materials developed here hold high potential for energy storage applications.
引用
收藏
页码:173 / 179
页数:7
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