Fine and coarse PM composition and sources in rural and urban sites in Switzerland: Local or regional pollution?

被引：100
作者：
Minguillon, M. C. [1 ,2 ]
Querol, X. [1 ]
Baltensperger, U. [2 ]
Prevot, A. S. H. [2 ]
机构：
[1] CSIC, Inst Environm Assessment & Water Res IDAEA, ES-08034 Barcelona, Spain
[2] Paul Scherrer Inst, Lab Atmospher Chem, CH-5232 Villigen, Switzerland
来源：
SCIENCE OF THE TOTAL ENVIRONMENT | 2012年 / 427卷
关键词：
PM1; PM10; Chemical composition; Metals; Source apportionment; Switzerland; SUBMICRON ORGANIC AEROSOLS; SOURCE APPORTIONMENT; PARTICULATE MATTER; CHEMICAL-COMPOSITION; TRACE-ELEMENTS; CARBON; PM2.5; PARTICLES; EMISSIONS; METALS;
D O I：
10.1016/j.scitotenv.2012.04.030
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
The chemical composition and sources of ambient particulate matter (PM) in Switzerland were studied. PM1 and PK10 samples were collected in winter and summer at an urban background site in Zurich and a rural background site in Payerne. Concentrations of major and trace elements, NO3-, SO42-, NH4+, organic and elemental carbon were determined. A subsequent Positive Matrix Factorization (PMF) analysis was performed. PM10, and PM1 concentrations varied similarly at both sites, with average PM10, concentrations 24-25 mu g/m(3) and 13-14 mu g/m(3) in winter and summer, respectively, and average PM, concentrations 12-17 mu g/m(3) and 6-7 mu g/m(3). The influence of local sources was found to be higher in winter. PM was dominated by nitrate and organic matter in winter, and by mineral matter and organic matter in summer. Trace element concentrations related to road traffic (Zn, Cu, Sb, Sn) were higher at Zurich. Concentrations of Tl and Cs, attributed to the influence of a glass industry, were higher at Payerne. The elements mainly present in the coarse fraction were those related to mineral matter and brake and tyre abrasion (Cu, Mn, Ti, Sb, Sr, Bi, Li, La, Nd), and those in the fine fraction were related to high temperature anthropogenic processes (Pb, As, Cd, Tl, Cs). Common PM1 and PM1-10 sources identified by PMF were: ammonium nitrate, present in winter, negligible in summer; ammonium sulfate + K(biomass burning) + road traffic; and road traffic itself, related to exhaust emissions in PM1 and to road dust resuspension in PM1-10. Size-fraction specific sources were: a PM1 glass industry source characterized by Cs, Tl, Rb, Li and Na, only present in Payerne; a PM1 background source characterized by V, Ni, sulfate and Fe; two PM1-10 mineral-related sources, with higher contribution in summer; a PM1-10 salt source; and a PM1-10 organic source, with higher contribution in summer, attributed to bioaerosols. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：191 / 202
页数：12
相关论文
共 45 条
  • [1] O/C and OM/OC ratios of primary, secondary, and ambient organic aerosols with high-resolution time-of-flight aerosol mass spectrometry
    Aiken, Allison C.
    Decarlo, Peter F.
    Kroll, Jesse H.
    Worsnop, Douglas R.
    Huffman, J. Alex
    Docherty, Kenneth S.
    Ulbrich, Ingrid M.
    Mohr, Claudia
    Kimmel, Joel R.
    Sueper, Donna
    Sun, Yele
    Zhang, Qi
    Trimborn, Achim
    Northway, Megan
    Ziemann, Paul J.
    Canagaratna, Manjula R.
    Onasch, Timothy B.
    Alfarra, M. Rami
    Prevot, Andre S. H.
    Dommen, Josef
    Duplissy, Jonathan
    Metzger, Axel
    Baltensperger, Urs
    Jimenez, Jose L.
    [J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2008, 42 (12) : 4478 - 4485
  • [2] Identification of the mass spectral signature of organic aerosols from wood burning emissions
    Alfarra, M. Rami
    Prevot, Andre S. H.
    Szidat, Sonke
    Sandradewi, Jisca
    Weimer, Silke
    Lanz, Valentin A.
    Schreiber, Daniel
    Mohr, Martin
    Baltensperger, Urs
    [J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2007, 41 (16) : 5770 - 5777
  • [3] Spatial and chemical patterns of PM10 in road dust deposited in urban environment
    Amato, F.
    Pandolfi, M.
    Viana, M.
    Querol, X.
    Alastuey, A.
    Moreno, T.
    [J]. ATMOSPHERIC ENVIRONMENT, 2009, 43 (09) : 1650 - 1659
  • [4] [Anonymous], J GEOPHYS RES ATMOS
  • [5] [Anonymous], CLIMATE CHANGE 2007
  • [6] [Anonymous], 2465 VDI
  • [7] One decade of parallel fine (PM2.5) and coarse (PM10-PM2.5) particulate matter measurements in Europe: trends and variability
    Barmpadimos, I.
    Keller, J.
    Oderbolz, D.
    Hueglin, C.
    Prevot, A. S. H.
    [J]. ATMOSPHERIC CHEMISTRY AND PHYSICS, 2012, 12 (07) : 3189 - 3203
  • [8] The weekly cycle of ambient concentrations and traffic emissions of coarse (PM10-PM2.5) atmospheric particles
    Barmpadimos, I.
    Nufer, M.
    Oderbolz, D. C.
    Keller, J.
    Aksoyoglu, S.
    Hueglin, C.
    Baltensperger, U.
    Prevot, A. S. H.
    [J]. ATMOSPHERIC ENVIRONMENT, 2011, 45 (27) : 4580 - 4590
  • [9] Influence of meteorology on PM10 trends and variability in Switzerland from 1991 to 2008
    Barmpadimos, I.
    Hueglin, C.
    Keller, J.
    Henne, S.
    Prevot, A. S. H.
    [J]. ATMOSPHERIC CHEMISTRY AND PHYSICS, 2011, 11 (04) : 1813 - 1835
  • [10] Epidemiological evidence of effects of coarse airborne particles on health
    Brunekreef, B
    Forsberg, B
    [J]. EUROPEAN RESPIRATORY JOURNAL, 2005, 26 (02) : 309 - 318
12345