Effect of addition of Proline, ionic liquid [Choline] [Pro] on CO2 separation properties of poly(amidoamine) dendrimer/poly(ethylene glycol) hybrid membranes

被引:0
|
作者
Duan, S. H. [1 ]
Kai, T.
Chowdhury, F. A.
Taniguchi, I. [2 ]
Kazama, S. [3 ]
机构
[1] Res Inst Innovat Technol Earth RITE, 9-2 Kizugawadai, Kizugawa, Kyoto 6190292, Japan
[2] Kyushu Univ, Int Inst Carbon Neutral Energy Res WPI I2CNER, Nishi Ku, 744 Motooka, Fukuoka, Fukuoka 8190395, Japan
[3] Nippon Steel Corp Ltd, Tech Dev Bur, Chiyoda Ku, 2-6-1 Marunouchi, Tokyo 1008071, Japan
关键词
DENDRIMER; CAPTURE;
D O I
10.1088/1757-899X/2921/1/012040
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Poly(amidoamine) (PAMAM) dendrimers were incorporated into cross-linked poly(ethylene glycol) (PEGDMA) matrix to improve carbon dioxide (CO2) separation performance at elevated pressures. In our previous studies, PAMAM/PEGDMA hybrid membranes showed high CO2 separation properties from CO2/H-2 mixed gases. In this study, proline, choline (a)nd ionic liquid [Choline][Pro] compounds were selected as rate promoters that were used to prepare PAMAM/PEGDMA hybrid membranes. The effect of addition of proline, choline, IL [Choline][Pro] on separation performance of PAMAM/PEGDMA) hybrid membranes for CO2/H-2 separation was investigated. Amino acid proline, choline, and IL [Choline] [Pro] were used to promote CO2 and amine reaction. With the addition of [Choline] [Pro] into PAMAM/PEG membrane, CO2 permeance of PAMAM/PEG hybrid membranes are increased up to 46% without any change of selectivity of membrane for CO2.
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页数:7
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